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Restricted Cosmetic Substances — Annex III

Annex III of EU Cosmetics Regulation 1223/2009 lists substances that may only be used under specific conditions. This grouped page currently contains 375 records with restriction logic, concentration limits, warnings or product-type conditions to review.

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Annex III records

375 total

Annex III 200

HC VIOLET NO. 2

1-Propanol, 3-[[4-[bis(2-hydroxyethyl)amino]-2-nitrophenyl]amino] (see note 17)

CAS: 104226-19-9EC: 410-910-3

Can cause allergic reaction

Max concentration Product type

Annex III 200

TETRAAMINOPYRIMIDINE SULFATE

2,4,5,6-Tetraaminopyrimidine sulphate

CAS: 5392-28-9EC: 226-393-0

(a) To be printed on the label: The mixing ratio. “Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not in…

Max concentration Product type

Annex III 201

2-CHLORO-6-ETHYLAMINO-4-NITROPHENOL

Phenol, 2-Chloro-6-(ethylamino)-4-nitro- (see note 17)

CAS: 131657-78-8EC: 411-440-1

Can cause allergic reaction

Max concentration Product type

Annex III 202

1,3-BIS-(2,4-DIAMINOPHENOXY)PROPANE

4,4'-[1,3-Propanediylbis(oxy)]bisbenzene-1,3-diamine and its tetrahydrochloride salt (see note 17)

CAS: 81892-72-0 - 74918-21-1EC: 279-845-4 - 278-022-7

(a) The mixing ratio: Hair colorants can cause severe allergic reactions. (b) Can cause allergic reaction

Product type

Annex III 203

6-METHOXY-2-METHYLAMINO-3-AMINOPYRIDINE HCL

6-Methoxy-N2-methyl-2,3-pyridinediamine hydrochloride and dihydrochloride salt

CAS: 90817-34-8 / 83732-72-3EC: - / 280-622-9

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type

Annex III 204

DIHYDROXYINDOLINE

2,3-Dihydro-1H-indole-5,6-diol and its hydrobromide salt (see note 17).

CAS: 29539-03-5 - 138937-28-7EC: - - 421-170-6

- Can cause allergic reaction - You have ever experienced any reaction afther colouring your hair - You have experienced a reaction to a temporary 'black henna…

Max concentration Product type

Annex III 205

4-HYDROXYPROPYLAMINO-3-NITROPHENOL

1-Hydroxy-3-nitro-4-(3-hydroxypropylamino)benzene (see note 17)

CAS: 92952-81-3EC: 406-305-9

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 206

HYDROXYETHYL-P-PHENYLENE-DIAMINE SULFATE

3-(2-Hydroxyethyl)-p- phenylenediammonium sulphate

CAS: 93841-25-9EC: 298-995-1

(a) To be printed on the label: The mixing ratio. “Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not in…

Product type

Annex III 207

DIHYDROXY-INDOLE

1H-Indole-5,6-diol

CAS: 3131-52-0EC: 412-130-9

To be printed on the label: Hair colorants can cause severe allergic reactions.

Product type

Annex III 208

HC ORANGE NO. 2

1-(beta-Aminoethyl)amino-4-(beta-hydroxyethyl)oxy-2-nitrobenzene and its salts

CAS: 85765-48-6EC: 416-410-1

Hair colorants can cause severe allergic reactions. Read and follow instructions. .

Max concentration Product type

Annex III 208

5-Amino-4-Chloro-o-Cresol HCl

5-Amino-4-chloro-2-methylphenol hydrochloride

CAS: 110102-85-7

To be printed on the label: Hair colorants can cause severe allergic reactions.

Product type

Annex III 209

6-Hydroxy-indole

1H-Indol-6-ol

CAS: 2380-86-1EC: 417-020-4

To be printied on the label: Hair colorants can cause severe allergic reactions.

Product type

Annex III 21

QUININE

Cinchonan-9-ol, 6'-methoxy-, (8.alpha.,9R)- its salts

CAS: 130-95-0EC: 205-003-2

(a) Hair rinse-off products (b) Hair leave-on products

Max concentration Product type

Annex III 210

ISATIN

1H-Indole-2,3-Dione

CAS: 91-56-5EC: 202-077-8

Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporar…

Max concentration Product type

Annex III 211

2-AMINO-3-HYDROXYPYRIDINE

2-Aminopyridin-3-ol; 2-Amino-3-Hydroxypyridine

CAS: 16867-03-1EC: 240-886-8

(a) To be printed on the label: The mixing ratio. “Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not in…

Product type

Annex III 212

1-Acetoxy-2-Methylnaph-thalene

2-Methyl-1-naphthyl acetate

CAS: 5697-02-9EC: 454-690-7

After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 2,0% (When both 2-Methyl-1-Naphthol and 1-Acetoxy-2-Methylnap…

Product type

Annex III 213

2-Methyl-1-Naphthol

1-Hydroxy-2-methylnaphthalene

CAS: 7469-77-4EC: 231-265-2

To be printed on the label: Hair colorants can cause severe allergic reactions.

Product type

Annex III 214

ACID YELLOW 1

Disodium 5,7-dinitro-8-oxido-2- naphthalenesulfonate CI 1036

CAS: 846-70-8EC: 212-690-2

To be printed on the label: Hair colorants can cause severe allergic reactions

Max concentration Product type

Annex III 215

4-AMINO-3-NITROPHENOL

4-Amino-3-nitrophenol

CAS: 610-81-1EC: 210-236-8

(a) and (b) “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age …

Max concentration Product type

Annex III 216

2,7-NAPHTHALENEDIOL

Naphthalene-2,7-diol

CAS: 582-17-2EC: 209-478-7

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 217

M-AMINOPHENOL; M-AMINOPHENOL HCL; M-AMINOPHENOL SULFATE

m-Aminophenol and its salts

CAS: 591-27-5/ 51-81-0 / 68239-81-6 /38171-54-9EC: 209-711-2 / 200-125-2 / 269-475-1

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Product type

Annex III 218

2,6-DIHYDROXY-3,4-DIMETHYLPYRIDINE

6-Hydroxy-3,4- dimethyl-2-pyridone

CAS: 84540-47-6EC: 283-141-2

To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended…

Product type

Annex III 219

4-Hydroxypropylamino-3-nitrophenol

1-Hydroxy-3-nitro- 4-(3-hydroxypropy lamino)benzene

CAS: 92952-81-3EC: 406-305-9

(a) To be printed on the label: The mixing ratio. ‘ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 22

RESORCINOL

1,3-benzenediol

CAS: 108-46-3EC: 203-585-2

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type

Annex III 220

HC Blue No 11

1-[(2′-Methoxye thyl)amino]-2-nitro- 4-[di-(2′-hydroxye thyl)amino]ben zene

CAS: 23920-15-2EC: 459-980-7

— Do not use with nitro sating agents — Maximum nitrosamine content: 50 μg /kg — Keep in nitrite-free containers

Max concentration Product type

Annex III 221

Hydroxyethyl-2-Nitro-p-Toluidine

2-(4-Methyl-2-nitroanilino)ethanol

CAS: 100418-33-5EC: 408-090-7

To be printed on the label: Hair colorants can use severe allergic reactions

Max concentration Product type

Annex III 222

2-HYDROXYETHYL PICRAMIC ACID

1-Hydroxy-2-beta-hydroxyethylamino-4,6-dinitrobenzene

CAS: 99610-72-7EC: 412-520-9

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type CMR

Annex III 223

P-METHYLAMINOPHENOL

4-Methylaminophenol and its salts

CAS: 150-75-4 - 55-55-0 - 1936-57-8EC: 205-768-2 - 200-237-1 - 217-706-1

Hair colourants can cause severe allergic reactions

Product type

Annex III 224

HC Violet No 2

1-Propanol, 3-[[4-[bis(2-hydroxyethyl)amino]-2-nitrophenyl]amino]

CAS: 104226-19-9EC: 410-910-3

Can cause allergic reaction

Max concentration Product type

Annex III 225

HC BLUE NO. 12

1-(beta-Hydroxyethyl)amino-2-nitro-4-N-ethyl-N-(beta-hydroxyethyl)aminobenzene and its hydrocloride

CAS: 104516-93-0 - 132885-85-9EC: 407-020-2

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 226

1,3-bis-(2,4-Diaminophenoxy)propane 1,3-bis-(2,4-Diaminophenoxy)propane HCl

4,4′-[1,3-Propanediylbis(oxy)]bisbenzene-1,3-diamine and its tetrahydrochloride salt

CAS: 81892-72-0 / 74918-21-1EC: 279-845-4 / 278-022-7

(a) To be printed on the label: The mixing ratio. ‘imageHair colourants can cause severe allergic reactions. Read and follow instructions. This product is not …

Max concentration Product type

Annex III 227

3-AMINO-2,4-DICHLOROPHENOL

3-Amino-2,4-dichlorophenol and its hydrochloride

CAS: 61693-42-3 - 1693-43-4EC: 262-909-0

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 228

PHENYL METHYL PYRAZOLONE

3-Methyl-1-phenyl-5-pyrazolone

CAS: 89-25-8EC: 201-891-0

To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended…

Product type

Annex III 229

2-METHYL-5-HYDROXYETHYL AMINOPHENOL

5-[(2-hydroxyethyl)amino]-o-cresol

CAS: 55302-96-0EC: 259-583-7

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Product type

Annex III 23

(a) Alkali sulphides (b) Alkaline earth sulphides

(a) (b) Keep out of reach of children Avoid contact with eyes

Max concentration Product type

Annex III 230

HYDROXYBENZOMORPHOLINE

2,3-Dihydro-2H-1,4-benzoxazin-6-ol

CAS: 26021-57-8EC: 247-415-5

To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended…

Product type

Annex III 231

HC YELLOW NO. 10

1,5-Di-(beta-hydroxyethylamino)-2-nitro-4-chlorobenzene (see note 17)

CAS: 109023-83-8EC: 416-940-3

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 microgram/kg - Keep in nitrite-free containers

Max concentration Product type

Annex III 232

2,6-DIMETHOXY-3,5-PYRIDINEDIAMINE HCL

3,5-Diamino-2,6-dimethoxypyridine and its salts

CAS: 56216-28-5 - 85679-78-3EC: 260-062-1

Can cause allergic reaction

Product type

Annex III 234

HC VIOLET NO 1

Ethanol, 2-[(4-amino-2-methyl-5-nitrophenyl)amino]- and its salts

CAS: 82576-75-8EC: 417-600-7

Hair colorants can cause severe allergic reactions. Read and follow instructions.

Max concentration Product type

Annex III 235

3-METHYLAMINO-4-NITROPHENOXYETHANOL

2-[3-(Methylamino)-4-nitrophenoxy]ethanol (see note 17)

CAS: 59820-63-2EC: 261-940-7

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 micrograme/Kg - Keep in nitrite-free containers

Max concentration Product type

Annex III 236

2-HYDROXYETHYLAMINO-5-NITROANISOLE

2-[(2-methoxy-4-nitrophenyl)amino]ethanol and its salts

CAS: 66095-81-6EC: 266-138-0

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 microgram/Kg - Keep in nitrite-free containers

Max concentration Product type

Annex III 237

HC RED NO 13

2,2'-[(4-Amino-3-nitrophenyl)imino]bisethanol hydrochloride and its salts

CAS: 29705-39-3 - 94158-13-1EC: -- 303-083-4

Hair colourants can cause seere allergic reactions Read and follow instructions

Max concentration Product type

Annex III 238

1,5-NAPHTHALENEDIOL

Naphthalene-1,5-diol and its salts

CAS: 83-56-7EC: 201-487-4

Hair colourants can cause severe allergic reactions Read and follow instrctions

Max concentration Product type

Annex III 239

HYDROXYPROPYL BIS(N-HYDROXYETHYL-P-PHENYLENEDIAMINE) HCL

Hydroxypropyl bis(N-hydroxyethyl-p-phenylenediamine) and its tetrahydro-chloride

CAS: 128729-30-6 -- 128729-28-2EC: 416-320-2

Hair colourants can cause severe allergic reactions Read and follow instructions

Product type

Annex III 24

ZINC ACETATE / ZINC CHLORIDE / ZINC GLUCONATE / ZINC GLUTAMATE

Water-soluble zinc salts with the exception of zinc 4- hydroxy-benzenesulphonate (entry 25) and zinc pyrithione (Annex II, entry 1670)

Max concentration

Annex III 240

4-Nitro-o-Phenylenediamine

4-Nitro-1,2-phenylenediamine

CAS: 99-56-9EC: 202-766-3

To be printing on the label: Hair colorants can cause severe allergic reactions.

Product type

Annex III 241

4-AMINO-2-HYDROXYTOLUENE

5-Amino-o-cresol

CAS: 2835-95-2EC: 220-618-6

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions.Read and follow instructions. This product is not intend…

Product type

Annex III 242

2,4-DIAMINOPHENOXYETHANOL HCL

2,4-Diaminophenoxyethanol, its hydrochloride and its sulphate

CAS: 70643-19-5 / 66422-95-5 / 70643-20-8EC: - / 266-357-1 / 274-713-2

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Product type

Annex III 243

2-METHYLRESORCINOL

1,3-benzenediol, 2-methyl

CAS: 608-25-3EC: 210-155-8

(a) To be printed on the label: The mixing ratio. “Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not in…

Max concentration Product type

Annex III 244

4-AMINO-M-CRESOL

4-Amino-m-cresol

CAS: 2835-99-6EC: 220-621-2

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Product type

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Annex III lists substances permitted only under defined conditions. This grouped view is built for quickly triaging 375 restricted-substance records before you open the full entry and check concentration limits, product scope and warnings.

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