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Permitted Cosmetic Colorants — Annex IV

Annex IV of EU Cosmetics Regulation 1223/2009 lists colorants approved for cosmetic use. This grouped page currently contains 154 colorant records to browse by name, identifier and annex conditions.

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Annex IV records

154 total
Annex IV 50

CI 24790

Disodium 4,6-dihydroxy-3-[[4-[1-[4-[[1-hydroxy-7-[(phenylsulphonyl)oxy]-3-sulphonato-2-naphthyl]azo]phenyl]cyclohexyl]phenyl]azo]naphthalene-2-sulphonate
CAS: 13421-53-9EC: 236-531-1
Max concentration
Annex IV 51

CI 26100 /SOLVENT RED 23

1-(4-(Phenylazo)phenylazo)-2-naphthol
CAS: 85-86-9EC: 201-638-4

Purity criteria: anilin

Max concentration
Annex IV 52

CI 27755

Tetrasodium 6-amino-4-hydroxy-3-[[7-sulphonato-4-[(4-sulphonatophenyl)azo]-1-naphthyl]azo]naphthalene-2,7-disulphonate
CAS: 2118-39-0EC: 218-326-9
Annex IV 53

CI 28440

Tetrasodium 1-acetamido-2-hydroxy-3-(4-((4-sulphonatophenylazo)-7-sulphonato-1-naphthylazo))naphthalene-4,6-disulphonate
CAS: 2519-30-4EC: 219-746-5

Purity criteria as set out in Commission Directive 95/45/EC (E 151)

Annex IV 54

CI 40215

Benzenesulfonic acid, 2,2'-(1,2-ethenediyl)bis-5-nitro-, disodium salt, reaction products with 4-[(4-aminophenyl)azo]benzenesulfonic acid, sodium salts
CAS: 1325-54-8EC: 215-397-8
Max concentration
Annex IV 55

CI 40800

beta Carotene
CAS: 116-32-5; 31797-85-0; 7235-40-7EC: 230-636-6

Purity criteria as set out in Commission Directive 95/45/EC (E 160a)

Annex IV 56

CI 40820

8'-apo-.beta.-Caroten-8'-al
CAS: 1962-15-8EC: 214-171-6

Purity criteria as set out in Commission Directive 95/45/EC (E 160e)

Annex IV 57

CI 40825

Ethyl 8'-apo-.beta.-caroten-8'-oate
CAS: 1109-11-1EC: 214-173-7

Purity criteria as set out in Commission Directive 95/45/EC (E 160f)

Annex IV 58

CI 40850

Canthaxanthin
CAS: 514-78-3EC: 208-187-2

Purity criteria as set out in Commission Directive 95/45/EC (E 161g)

Annex IV 59

CI 42045 /ACID BLUE 1

Ammonium, (4-(alpha-(p-(diethylamino)phenyl)-2,4-disulfobenzylidene)-2,5-cyclohexadien-1-ylidene)diethyl-, hydroxide, monosodium salt
CAS: 129-17-9EC: 204-934-1
Max concentration
Annex IV 6

CI 11725

2-[(4-Methoxy-2-nitrophenyl)azo]-3-oxo-N-(o-tolyl)butyramide
CAS: 6371-96-6EC: 228-907-9
Max concentration
Annex IV 60

CI 42051 /ACID BLUE 3

Ethanaminium, N-(4-((4-(diethylamino)phenyl)(5-hydroxy-2,4-disulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-N-ethylhydroxide, inner salt, calcium salt (2:1) and its insoluble…
CAS: 3536-49-0EC: 222-573-8

Purity criteria as set out in Commission Directive 95/45/EC (E 131)

Annex IV 61

CI 42053/ FAST GREEN FCF

Benzene-methanaminium, N-ethyl-N-(4-((4-(ethyl((3-sulfophenyl)methyl)amino)phenyl)(4-hydroxy-2-sulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-3-sulfo-, hydroxide, inner salt,…
CAS: 2353-45-9EC: 219-091-5
Annex IV 62

CI 42080

Hydrogen (benzyl)[4-[[4-[benzylethylamino]phenyl](2,4-disulphonatophenyl)methylene]cyclohexa-2,5-dien-1-ylidene](ethyl)ammonium, sodium salt
CAS: 3486-30-4EC: 222-476-0
Max concentration
Annex IV 63

CI 42090/ ACID BLUE 9; ACID BLUE 9 AMMONIUM SALT; ACID BLUE 9 ALUMINUM LAKE

Benzenemethanaminium, N-ethyl-N-(4-((4-(ethyl((3-sulfophenyl)methyl)amino)phenyl)(2-sulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-3-sulfo-, hydroxide, inner salt, disodium s…
CAS: 2650-18-2; 37307-56-5; 3844-45-9EC: 223-339-8

Purity criteria as sset out in Commission Directive 95/45/EC (E 133)

Annex IV 64

CI 42100

Hydrogen [4-[(2-chlorophenyl)[4-[ethyl(3-sulphonatobenzyl)amino]phenyl]methylene]cyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt
CAS: 4857-81-2EC: 225-458-0
Max concentration
Annex IV 65

CI 42170

Hydrogen [4-[(2-chlorophenyl)[4-[ethyl(3-sulphonatobenzyl)amino]-o-tolyl]methylene]-3-methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt
CAS: 5863-51-4EC: 227-513-4
Max concentration
Annex IV 66

CI 42510

(4-(4-Aminophenyl)(4-iminocyclohexa-2,5-dienylidene)methyl)-2-methylaniline hydrochloride
CAS: 632-99-5EC: 211-189-6
Max concentration
Annex IV 67

CI 42520 / BASIC VIOLET 2

4-[(4-Amino-m-tolyl)(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]-o-toluidine monohydrochloride
CAS: 3248-91-7EC: 221-831-7

5 ppm

Max concentration
Annex IV 68

CI 42735

Hydrogen [4-[[4-(diethylamino)phenyl][4-[ethyl[(3-sulphonatobenzyl)amino]-o-tolyl]methylene]-3-methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt
CAS: 6505-30-2EC: 229-390-2
Max concentration
Annex IV 69

CI 44045

[4-[[4-Anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride
CAS: 2580-56-5EC: 219-943-6
Max concentration
Annex IV 7

CI 11920

4-(Phenylazo)resorcinol
CAS: 2051-85-6EC: 218-131-9
Annex IV 70

CI 44090

Hydrogen [4-[4-(dimethylamino)-.alpha.-(2-hydroxy-3,6-disulphonato-1-naphthyl)benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium, monosodium salt
CAS: 3087-16-9EC: 221-409-2

Purity criteria as set out in Commission Directive 95/45/EC (E 142)

Annex IV 71

CI 45100/ ACID RED 52

Hydrogen 3,6-bis(diethylamino)-9-(2,4-disulphonatophenyl)xanthylium, sodium salt
CAS: 3520-42-1EC: 222-529-8
Max concentration
Annex IV 72

CI 45190 / ACID VIOLET 9

Hydrogen 9-(2-carboxylatophenyl)-3-(2-methylanilino)-6-(2-methyl-4-sulphoanilino)xanthylium, monosodium salt
CAS: 6252-76-2EC: 228-377-9
Max concentration
Annex IV 73

CI 45220

Hydrogen 9-(2,4-disulphonatophenyl)-3,6-bis(ethylamino)-2,7-dimethylxanthylium, monosodium salt
CAS: 5873-16-5EC: 227-528-6
Max concentration
Annex IV 74

CI 45350

Disodium 2-(3-oxo-6-oxidoxanthen-9-yl)benzoate
CAS: 518-45-6; 518-47-8EC: -; 208-253-0

6%

Annex IV 75

CI 45370

4',5'-Dibromo-3',6'-dihydroxyspiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 596-03-2; 4372-02-5EC: 209-876-0; 224-468-2

Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid

Annex IV 76

CI 45380 / ACID RED 87

Disodium 2-(2,4,5,7-tetrabromo-6-oxido-3-oxoxanthen-9-yl)benzoate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 17372-87-1 / 548-26-5 / 15876-39-8 / 15086-94-9 / 94021-89-3EC: 241-409-6 / - / 240-005-7 / 239-138-3 / 301-481-2

Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid

Annex IV 77

CI 45396

3',6'-Dihydroxy-4',5'-dinitrospiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one
CAS: 24545-86-6EC: 246-308-0

Only in free acid form, when used in lip products

Annex IV 78

CI 45405

Dipotassium 3,6-dichloro-2-(2,4,5,7-tetrabromo-6-oxido-3-oxoxanthen-9-yl)benzoate
CAS: 6441-77-6EC: 229-225-4

Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid

Max concentration
Annex IV 79

CI 45410

3,4,5,6-Tetrachloro-2-(1,4,5,8-tetrabromo-6-hydroxy-3-oxoxanthen-9-yl)benzoic acid and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 18472-87-2EC: 242-355-6

Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid

Annex IV 8

CI 12010

4-[(4-Ethoxyphenyl)azo]naphthol
CAS: 6535-42-8EC: 229-439-8
Max concentration
Annex IV 80

CI 45430

Disodium 2-(2,4,5,7-tetraiodo-6-oxido-3-oxoxanthen-9-yl)benzoate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 12227-78-0EC: 240-474-8

Purity criteria as set out in Commission Directive 95/45/EC (E 127)

Annex IV 81

CI 47000 / SOLVENT YELLOW 33

1,3-Isobenzofurandione, reaction products with methylquinoline and quinoline
CAS: 8003-22-3EC: 232-318-2
Max concentration
Annex IV 82

CI 47005

1H-Indene-1,3(2H)-dione, 2-(2-quinolinyl)-, sulfonated, sodium salts
CAS: 38615-46-2 ; 8004-92-0; 95193-83-2EC: -; -; 305-897-5

Purity criteria as set out in Commission Directive 95/45/EC (E 104)

Annex IV 83

CI 50325

Hydrogen 9-[(3-methoxyphenyl)amino]-7-phenyl-5-(phenylamino)-4,10-disulphonatobenzo[a]phenazinium, sodium salt
CAS: 6837-46-3; 6856-08-2EC: -; 229-951-1
Max concentration
Annex IV 84

CI 50420

Sulfonated nigrosine color
CAS: 8005-03-6
Max concentration
Annex IV 85

CI 51319 / PIGMENT VIOLET 23

8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo[3,2-b:3',2'-m]triphenodioxazine
CAS: 6358-30-1EC: 28-767-9
Max concentration
Annex IV 87

CI 59040

Trisodium 8-hydroxypyrene-1,3,6-trisulphonate
CAS: 6358-69-6EC: 228-783-6
Max concentration
Annex IV 88

CI 60724

1-Anilino-4-hydroxyanthraquinone
CAS: 19286-75-0EC: 242-939-0
Max concentration
Annex IV 9

CI 12085

1-[(2-Chloro-4-nitrophenyl)azo]-2-naphthol and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 2814-77-9EC: 220-562-2

3%

Annex IV 90

CI 60730

Sodium 4-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthryl)amino]toluene-3-sulphonate
CAS: 4430-18-6EC: 224-618-7
Max concentration
Annex IV 91

CI 61565

1,4-bis(p-Tolylamino)anthraquinone
CAS: 128-80-3EC: 204-909-5
Annex IV 92

CI 61570

Disodium 2,2'-(9,10-dioxoanthracene-1,4-diyldiimino)bis(5-methylsulphonate)
CAS: 4403-90-1EC: 224-546-6
Annex IV 93

CI 61585

Sodium 3,3'-(9,10-dioxoanthracene-1,4-diyldiimino)bis(2,4,6-trimethylbenzenesulphonate)
CAS: 4474-24-2EC: 224-748-4
Max concentration
Annex IV 94

CI 62045

Sodium 1-amino-4-(cyclohexylamino)-9,10-dihydro-9,10-dioxoanthracene-2-sulphonate
CAS: 4368-56-3EC: 224-460-9
Max concentration
Annex IV 95

CI 69800

6,15-Dihydroanthrazine-5,9,14,18-tetrone
CAS: 81-77-6EC: 201-375-5

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Annex IV is the positive list of colorants permitted for use in cosmetic products. This grouped view gives you 154 colorant records to compare by name, CI context, identifiers and linked conditions.

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