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Permitted Cosmetic Colorants — Annex IV

Annex IV of EU Cosmetics Regulation 1223/2009 lists colorants approved for cosmetic use. This grouped page currently contains 154 colorant records to browse by name, identifier and annex conditions.

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Annex IV records

154 total
Annex IV 143

TITANIUM DIOXIDE/CI 77891

Titanium Dioxide/CI 77891
CAS: 13463-67-7EC: 236-675-5

— Purity criteria as set out in Commission Directive 95/45/E (E 171) — Titanium dioxide in powder form containing 1 % or more of particles with aerodynamic di…

Annex IV 144

ZINC OXIDE

Zinc oxide
CAS: 1314-13-2EC: 215-222-5

Not to be used in applications that may lead to exposure of the end-user's lungs by inhalation.

Annex IV 145

LACTOFLAVIN / RIBOFLAVIN

Riboflavin
EC: 201-507-1 / 204-988-6

Purity criteria as set out in Commission Directive 95/45/EC (E101)

Annex IV 146

CARAMEL

Caramel
EC: 232-435-9

Purity criteria as set out in Commission Directive 95/45/EC (E150a-d)

Annex IV 147

CAPSANTHIN, CAPSORUBIN

Paprika extract, Capsanthin, capsorubin
EC: 207-364-1 / 207-425-2

Purity criteria as set out in Commission Directive 95/45/EC (E160c)

Annex IV 148

BEETROOT RED

Beetroot red
CAS: 7659-95-2; 89957-88-0; 89957-89-1EC: 231-628-5; 289-609-2; 289-610-8

Purity criteria as set out in Commission Directive 95/45/EC (E162)

Annex IV 149

ANTHOCYANINS

Anthocyanins (Cyanidin, Peonidin, Malvidin, Delphinidin, Petunidin, Pelargonidin)
CAS: 528-58-5 / 134-01-0 / 528-53-0 / 643-84-5 / 134-04-3EC: 208-438-6 / 205-125-6 / 211-403-8 / 208-437-0 / - / 205-127-7

Purity criteria as set out in Commission Directive 95/45/EC (E163)

Annex IV 15

CI 12700

2,4-Dihydro-5-methyl-2-phenyl-4-(phenylazo)-3H-pyrazol-3-one
CAS: 4314-14-1EC: 224-330-1
Max concentration
Annex IV 151

BROMOTHYMOL BLUE

Phenol, 4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis[2-bromo-3-methyl-6-(1-methylethyl)-, S,S-dioxide
CAS: 76-59-5EC: 200-971-2
Max concentration
Annex IV 152

BROMOCRESOL GREEN

Phenol, 4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis[2,6-dibromo-3-methyl-,S,S-dioxide
CAS: 76-60-8EC: 200-972-8
Max concentration
Annex IV 153

ACID RED 195

Sodium 4-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-3-hydroxynaphthalene-1-sulphonate
CAS: 12220-24-5
Max concentration
Annex IV 16

CI 13015

Disodium 2-amino-5-[(4-sulphonatophenyl)azo]benzenesulphonate
CAS: 2706-28-7EC: 220-293-0
Annex IV 17

CI 14270

Sodium 4-(2,4-dihydroxyphenylazo)benzenesulphonate
CAS: 547-57-9EC: 208-924-8
Annex IV 18

PONCEAUX SX (CI 14700)

Disodium 3-[(2,4-dimethyl-5- sulphonatophenyl)azo]-4- hydroxynaphthalene-1- sulphonate
CAS: 4548-53-2EC: 224-909-9
Annex IV 19

CI 14720

Disodium 4-hydroxy-3-[(4-sulphonatonaphthyl)azo]naphthalenesulphonate
CAS: 3567-69-9EC: 222-657-4

Purity criteria as set out in Commission Directive 95/45/EC (E 122)

Annex IV 2

CI 10020

Trisodium tris[5,6-dihydro-5-(hydroxyimino)-6-oxonaphthalene-2-sulphonato(2-)-N5,O6]ferrate(3-)
CAS: 19381-50-1EC: 243-010-2
Max concentration
Annex IV 20

CI 14815

Disodium 6-[(2,4-dimethyl-6-sulphonatophenyl)azo]-5-hydroxynaphthalene-1-sulphonate
CAS: 3257-28-1EC: 221-856-3
Annex IV 21

CI 15510

Sodium 4-[(2-hydroxy-1-naphthyl)azo]benzenesulphonate and its unsoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 633-96-5EC: 211-199-0
Max concentration
Annex IV 22

CI 15525

Calcium disodium bis[2-chloro-5-[(2-hydroxy-1-naphthyl)azo]-4-sulphonatobenzoate]
CAS: 5850-80-6EC: 227-456-5
Annex IV 23

CI 15580

Barium bis[4-[(2-hydroxy-1-naphthyl)azo]-2-methylbenzenesulphonate]
CAS: 5850-87-3EC: 227-459-1
Annex IV 24

CI 15620

Sodium 4-[(2-Hydroxy-1-naphthyl)azo]naphthalenesulphonate
CAS: 1658-56-6EC: 216-760-3
Max concentration
Annex IV 25

CI 15630

Sodium 2-[(2-hydroxynaphthyl)azo]naphthalenesulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 1248-18-6EC: 214-998-2

3%

Annex IV 26

CI 15800

Calcium bis[3-hydroxy-4-(phenylazo)-2-naphthoate]
CAS: 6371-76-2EC: 228-899-7
Max concentration
Annex IV 27

CI 15850

Disodium 3-hydroxy-4-[(4-methyl-2-sulphonatophenyl)azo]-2-naphthoate and its insoluble barium, strontium and zirconium lakes, salts and pigments
EC: 226-109-5

Purity criteria as set out in Commission Directive 95/45/EC (E 180)

Annex IV 28

CI 15865

Disodium 4-[(5-chloro-4-methyl-2-sulphonatophenyl)azo]-3-hydroxy-2-naphthoate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 3564-21-4; 5280-66-0EC: 222-642-2
Annex IV 29

CI 15880

Calcium 3-hydroxy-4-[(1-sulphonato-2-naphthyl)azo]-2-naphthoate
CAS: 6417-83-0EC: 229-142-3
Annex IV 3

CI 10316

Disodium 5,7-dinitro-8-oxidonaphthalene-2-sulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 846-70-8EC: 212-690-2
Max concentration
Annex IV 30

CI 15980

Disodium 6-hydroxy-5-[(3-sulphonatophenyl)azo]naphthalene-2-sulphonate
CAS: 2347-72-0EC: 219-073-7
Annex IV 31

CI 15985

Disodium 6-hydroxy-5-[(4-sulphonatophenyl)azo]naphthalene-2-sulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 2783-94-0EC: 220-491-7

Purity criteria as set out in Commission Directive 95/45/EC (E 110)

Annex IV 32

CI 16035

Disodium 6-hydroxy-5-[(2-methoxy-4-sulphonato-m-tolyl)azo]naphthalene-2-sulphonate
CAS: 25956-17-6EC: 247-368-0

Purity criteria as set out in Commission Directive 95/45/EC (E 129)

Annex IV 33

CI 16185

Trisodium 3-hydroxy-4-(4'-sulphonatonaphthylazo)naphthalene-2,7-disulphonate
CAS: 642-59-1; 915-67-3EC: 211-385-1; 213-022-2

Purity criteria as set out in Commission Directive 95/45/EC (E 123)

Annex IV 34

CI 16230

Disodium 7-hydroxy-8-(phenylazo)naphthalene-1,3-disulphonate
CAS: 1936-15-8EC: 217-705-6
Max concentration
Annex IV 35

CI 16255

Trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene-4',6,8-trisulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 2611-82-7EC: 220-036-2

Purity criteria as set out in Commission Directive 95/45/EC (E 124)

Annex IV 36

CI 16290

Tetrasodium 7-hydroxy-8-[(4-sulphonato-1-naphthyl)azo]naphthalene-1,3,6-trisulphonate
CAS: 5850-44-2EC: 227-454-4
Annex IV 37

CI 17200

Disodium 5-amino-4-hydroxy-3-(phenylazo)naphthalene-2,7-disulphonate and its unsoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 3567-66-6EC: 222-656-9
Annex IV 38

CI 18050

Disodium 5-acetylamino-4-hydroxy-3-(phenylazo)naphthalene-2,7-disulphonate
CAS: 3734-67-6EC: 223-098-9

Purity criteria as set out in Commission Directive 95/45/EC (E 128)

Max concentration
Annex IV 39

CI 18130

2,7-Naphthalenedisulfonic acid, 3-((4-cyclohexyl-2-methylphenyl)azo)-4-hydroxy-5-(((4-methylphenyl)sulfonyl)amino)-, disodium salt
CAS: 10236-37-0
Max concentration
Annex IV 4

CI 11680

2-[(4-Methyl-2-nitrophenyl)azo]-3-oxo-N-phenylbutyramide
CAS: 2512-29-0EC: 219-730-8
Max concentration
Annex IV 40

CI 18690

Hydrogen bis[2-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]benzoato(2-)]chromate(1-)
CAS: 5601-29-6EC: 227-022-5
Max concentration
Annex IV 41

CI 18736

Disodium hydrogen bis[5-chloro-3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-2-hydroxybenzenesulphonato(3-)]chromate(3-)
CAS: 6408-26-0EC: 229-051-9
Max concentration
Annex IV 42

CI 18820

Sodium 4-(3-hydroxy-5-methyl-4-phenylazopyrazol-2-yl)benzenesulphonate
CAS: 6359-82-6EC: 228-808-0
Max concentration
Annex IV 43

CI 18965

Disodium 2,5-dichloro-4-(5-hydroxy-3-methyl-4-((sulphophenyl)azo)pyrazol-1-yl)benzenesulphonate
CAS: 6359-98-4EC: 228-819-0
Annex IV 44

CI 19140

Trisodium 5-hydroxy-1-(4-sulphophenyl)-4-((4-sulphophenyl)azo)pyrazole-3-carboxylate and its insoluble barium, strontium and zirconium lakes, salts and pigments
CAS: 12225-21-7; 1934-21-0EC: 235-428-9; 217-699-5

Purity criteria as set out in Commission Directive 95/45/EC (E 102)

Annex IV 45

CI 20040

N,N'-(3,3'-Dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[2-[(2,4-dichlorophenyl)azo]-3-oxobutyramide]
CAS: 5979-28-2EC: 227-783-3

Maximum 3,3'-dimethylbenzidine concentration in the colouring agent: 5 ppm

Max concentration
Annex IV 46

CI 20470

Sodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-(phenylazo)naphthalene-2,7-disulphonate
CAS: 1064-48-8EC: 213-903-1
Max concentration
Annex IV 47

CI 21100

2,2'-[(3,3'-Dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)-3-oxobutyramide]
CAS: 5102-83-0EC: 225-822-9

Maximum 3,3'-dimethylbenzidine concentration in the colouring agent: 5 ppm

Max concentration
Annex IV 48

CI 21108

2,2'-[(3,3'-Dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(4-chloro-2,5-dimethoxyphenyl)-3-oxobutyramide]
CAS: 5567-15-7EC: 226-939-8

Maximum 3,3'-dimethylbenzidine concentration in the colouring agent: 5 ppm

Max concentration
Annex IV 49

CI 21230 /SOLVENT YELLOW 29

2,2'-[Cyclohexylidenebis[(2-methyl-4,1-phenylene)azo]]bis[4-cyclohexylphenol]
CAS: 6706-82-7EC: 229-754-0
Max concentration
Annex IV 5

CI 11710

2-[(4-Chloro-2-nitrophenyl)azo]-N-(2-chlorophenyl)-3-oxobutyramide
CAS: 6486-23-3EC: 229-355-1
Max concentration

How to use this grouped view

Annex IV is the positive list of colorants permitted for use in cosmetic products. This grouped view gives you 154 colorant records to compare by name, CI context, identifiers and linked conditions.

Open individual records to review Colour Index numbers, chemical identifiers and any applicable restrictions on product type or application.