EU cosmetic ingredients, restrictions and safety

Annex V Entry 1a 16/10/2010

AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE

Salts of benzoic acid other than that listed under reference number 1 and esters of benzoic acid

AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE appears in Annex V as a positive-list preservative entry for EU cosmetics. Maximum concentration in this record: 0.5% (acid).

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Permitted preservative— Annex V, EU Regulation 1223/2009

Max conc.: 0.5% (acid)

Entry: 1a

Record details

Maximum concentration

0.5% (acid)

INCI glossary name

AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE

Chemical name

Salts of benzoic acid other than that listed under reference number 1 and esters of benzoic acid

Regulatory information

Regulation

(EC) 2009/1223

Identified ingredients

Key data

CAS

1863-63-4 /2090-05-3 / 582-25-2 / 553-70-8 / 4337-66-0 / 93-58-3 / 93-89-0 / 2315-68-6 / 136-60-7 / 1205-50-3 / 939-48-0 / 93-99-2

EC

217-468-9 / 218-235-4 / 209-481-3 / 209-045-2 / 224-387-2 / 202-259-7 / 202-284-3 / 219-020-8 / 205-252-7 / 204-401-3 / 213-361-6 / 202-293-2

Annex

Entry number

1a

Inventory links for AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE

Inventory Restriction reference

Ref 31845

AMMONIUM BENZOATE

CAS: 1863-63-4

EC: 217-468-9

Inventory Restriction reference

Ref 31706

BUTYL BENZOATE

CAS: 136-60-7

EC: 205-252-7

Inventory Restriction reference

Ref 32313

CALCIUM BENZOATE

CAS: 2090-05-3

EC: 218-235-4

Inventory Restriction reference

Ref 33810

ETHYL BENZOATE

CAS: 93-89-0

EC: 202-284-3

Inventory Restriction reference

Ref 34602

ISOBUTYL BENZOATE

CAS: 120-50-3

EC: 204-401-3

Inventory Restriction reference

Ref 34684

ISOPROPYL BENZOATE

CAS: 939-48-0

EC: 213-361-6

Inventory Restriction reference

Ref 35084

MAGNESIUM BENZOATE

CAS: 553-70-8

EC: 209-045-2

Inventory Restriction reference

Ref 35180

MEA-BENZOATE

CAS: 4337-66-0

EC: 224-387-2

Inventory Restriction reference

Ref 35279

METHYL BENZOATE

CAS: 93-58-3

EC: 202-259-7

Inventory Restriction reference

Ref 36525

PHENYL BENZOATE

CAS: 93-99-2

EC: 202-293-2

Inventory Restriction reference

Ref 36934

POTASSIUM BENZOATE

CAS: 582-25-2

EC: 209-481-3

Inventory Restriction reference

Ref 37266

PROPYL BENZOATE

CAS: 2315-68-6

EC: 219-020-8

Direct matches are limited for this record, so nearby entries from Annex V are shown as well.

Annex V 1

Nearby record in the same annex

BENZOIC ACID; SODIUM BENZOATE

CAS: 65-85-0 / 532-32-1

EC: 200-618-2 / 208-534-8

Annex V 2

Nearby record in the same annex

PROPIONIC ACID / AMMONIUM PROPIONATE / CALCIUM PROPIONATE / MAGNESIUM PROPIONATE / POTASSIUM PROPIO…

CAS: 79-09-4 / 17496-08-1 / 4075-81-4 / 557-27-7 / 327-62-8 / 137-40-6

EC: 201-176-3 / 241-503-7 / 223-795-8 / 209-166-0 / 206-323-5 / 205-290-4

Annex V 3

Nearby record in the same annex

SALICYLIC ACID, CALCIUM SALICYLATE, MAGNESIUM SALICYLATE, MEA- SALICYLATE, SODIUM SALICYLATE, POTAS…

CAS: 69-72-7[1]/ 824-35-1[2]/ 18917-89-0[3]/ 59866-70-5[4]/ 54-21-7[5]/ 578-36-9[6]/ 2174-16-5[7]

EC: 200-712-3[1]/ 212-525-4[2]/ 242-669-3[3]/ 261-963-2[4]/ 200-198-0[5]/ 209-421-6[6]/ 218-531-3[7]

Annex V 4

Nearby record in the same annex

SORBIC ACID / CALCIUM SORBATE / SODIUM SORBATE / POTASSIUM SORBATE

CAS: 110-44-1 / 7492-55-9 / 7757-81-5 / 24634-61-5

EC: 203-768-7 / 231-321-6 / 231-819-3 / 246-376-1

Annex V 7

Nearby record in the same annex

o-Phenylphenol, Sodium o-Phenylphenate

CAS: 90-43-7, 132-27-4

EC: 201-993-5, 205-055-6

Annex V 9

Nearby record in the same annex

SODIUM SULFITE / AMMONIUM BISULFITE / AMMONIUM SULFITE / POTASSIUM SULFITE / POTASSIUM hydrogen SUL…

CAS: 7757-83-7 / 10192-30-0 / 10196-04-0 / 10117-38-1 / 7773-03-7 / 7631-90-5 / 7681-57-4 / 16731-55-8

EC: 231-821-4 / 233-469-7 / 233-484-9 / 233-321-1 / 231-870-1 /231-548-0 / 231-673-0 / 240-795-3

Annex V 11

Nearby record in the same annex

CHLOROBUTANOL

CAS: 57-15-8

EC: 200-317-6

Annex V 12 a

Nearby record in the same annex

BUTYLPARABEN/PROPYLPARABEN/SODIUM PROPOYLPARABEN/SODIUM BUTYLPARABEN/POTASSIUM BUTYLPARABEN/POTASSI…

CAS: 94-26-8/ 94-13-3/ 35285-69-9/ 36457-20-2/ 38566-94-8/ 84930-16-5

EC: 202-318-7/ 202-307-7/ 252-488-1/ 253-049-7/ 254-009-1/ 284-597-5

Annex V 12

Nearby record in the same annex

4-HYDROXYBENZOIC ACID / METHYLPARABEN /POTASSIUM ETHYLPARABEN /POTASSIUM PARABEN /SODIUM METHYLPARA…

CAS: 99-96-7 /99-76-3 /36457-19-9 /16782-08-4 /5026-62-0 /35285-68-8 /120-47-8 /114-63-6 /26112-0-2 /69959-44-0

EC: 202-804-9 /202-785-7 /253-048-1 /240-830-2 /225-714-1 /252-487-6 /204-399-4 /204-051-1 /247-464-2 /274-235-4

Annex V 13

Nearby record in the same annex

Dehydroacetic acid / SODIUM DEHYDROACETATE

CAS: 520-45-6 / 4418-26-2 / 16807-48-0

EC: 208-293-9 / 224-580-1 / -

Annex V 14

Nearby record in the same annex

FORMIC ACID / SODIUM FORMATE

CAS: 64-18-6 / 141-53-7

EC: 200-579-1 / 205-488-0

Annex V 15

Nearby record in the same annex

Dibromohexamidine isethionate

CAS: 93856-83-8

EC: 299-116-4

What Annex V means for AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE

AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE is an approved preservative listed in Annex V of EU Cosmetics Regulation 1223/2009. Only substances on this positive list may be used as cosmetic preservatives in the EU.

Each preservative entry specifies maximum permitted concentrations and applicable product scope. Concentrations must not exceed the listed maximum. Some preservatives require warning statements on the product label.

This record is linked to 12 CosIng inventory ingredients for name and identifier cross-reference. The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

Use concentration must not exceed: 0.5% (acid)
Verify the preservative is effective at the permitted concentration for your matrix.

Frequently asked questions

Yes. AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE is listed in Annex V of EU Cosmetics Regulation 1223/2009 as a permitted preservative. It may be used in cosmetics up to the maximum concentration specified above, within the permitted product scope.

CAS 1863-63-4 /2090-05-3 / 582-25-2 / 553-70-8 / 4337-66-0 / 93-58-3 / 93-89-0 / 2315-68-6 / 136-60-7 / 1205-50-3 / 939-48-0 / 93-99-2 is the unique numerical identifier assigned to AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

The maximum concentration of 0.5% (acid) applies to the concentration of the substance in the ready-to-use cosmetic product. When the substance is supplied as part of a blend or mixture, the calculation must account for the contribution of all sources in the formulation. The combined concentration must not exceed the stated limit.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.

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Source note for Annex V record AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE

This page summarizes one Annex V record for AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex V conditions for AMMONIUM BENZOATE / BUTYL BENZOATE / CALCIUM BENZOATE / ETHYL BENZOATE / ISOBUTYL BENZOATE / ISOPROPYL BENZOATE / MAGNESIUM BENZOATE / MEA-BENZOATE / METHYL BENZOATE / PHENYL BENZOATE / POTASSIUM BENZOATE / PROPYL BENZOATE, but confirm any final regulatory decision against the current official annex wording and source files.

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