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Annex II Entry 1763 15/01/2026

tert-butyl 2-ethylperoxyhexanoate

tert-butyl 2-ethylperoxyhexanoate is listed in Annex II as a prohibited substance for cosmetic products placed on the EU market.

Prohibited substance— Annex II, EU Regulation 1223/2009
Entry: 1763

Chemical identity and properties

PubChem 2D chemical structure for CAS 3006-82-4
CAS 3006-82-4PubChem CID 102924

tert-Butyl peroxy-2-ethylhexanoate

This peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported with inert solids to mitigate the explosion hazard. CAMEO Chemicals

IUPAC name
tert-butyl 2-ethylhexaneperoxoate
Molecular formula
C12H24O3
Molecular weight
216.32 g/mol
Exact mass
216.17254462 Da
XLogP3
4.0
Topological polar surface area
35.5 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
3
Covalent units
1
Defined stereocentres
0

Also known as

Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl estertert-Butyl 2-ethylperoxyhexanoateKGA9W7ZS5IINTEROX TBPEHPERCURE OUNII-KGA9W7ZS5ICHALOXYD P 13102-ETHYLHEXANOYL TERT-BUTYL PEROXIDE
16 more reported names
tert-butyl 2-ethylperhexanoatePeroxyhexanoic acid, 2-ethyl-, tert-butyl esterEINECS 221-110-7EC 221-110-7Trigonox 21TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE)TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, [TECHNICALLY PURE]Esperox 28LUPERSOL PDOPERBUTYL OTRIGONOX 21SRefChem:188214TRIGONOX T 21SCHALOXYD P 13272-Ethyl-hexaneperoxoic acid 1,1-dimethylethyl esterWYKYCHHWIJXDAO-UHFFFAOYSA-N
External database identifiers

Retrieved from NIH PubChem on 2026-08-31 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Record details

Chemical name

tert-butyl 2-ethylperoxyhexanoate

Regulatory information

Regulation

(EU) 2026/78

See every entry this act set

Key data

Annex
Entry number
1763

Direct matches are limited for this record, so nearby entries from Annex II are shown as well.

Annex II 1764
Nearby record in the same annex

Trimethyl borate

CAS: 121-43-7
EC: 204-468-9
Annex II 1754
Nearby record in the same annex

Acetone oxime

CAS: 127-06-0
EC: 204-820-1

What Annex II means for tert-butyl 2-ethylperoxyhexanoate

tert-butyl 2-ethylperoxyhexanoate is listed as a prohibited substance under Annex II of EU Cosmetics Regulation 1223/2009 and must not be intentionally added. Article 17 separately addresses unintended small quantities that are technically unavoidable under good manufacturing practice and compatible with the Article 3 safety requirement.

Formulators must screen their ingredients and raw materials to ensure none contain this substance. Suppliers should provide documentation confirming absence when requested.

The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

  • Verify this substance is absent from all raw materials and finished formulations.
  • Request absence confirmation or CoA from raw material suppliers.
  • Document the screening result in the Product Information File (PIF).

Frequently asked questions

Yes. tert-butyl 2-ethylperoxyhexanoate is listed in Annex II of EU Cosmetics Regulation 1223/2009 and is prohibited as an intentionally added cosmetic ingredient. Article 17 provides a narrow exception for unintended small quantities that are technically unavoidable under good manufacturing practice, provided the product remains safe under Article 3.

CAS 3006-82-4 is the unique numerical identifier assigned to tert-butyl 2-ethylperoxyhexanoate by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.

Source note for Annex II record tert-butyl 2-ethylperoxyhexanoate

This page summarizes one Annex II record for tert-butyl 2-ethylperoxyhexanoate from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex II conditions for tert-butyl 2-ethylperoxyhexanoate, but confirm any final regulatory decision against the current official annex wording and source files.

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