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Restricted substances

Browse Annex III restricted substances, warnings and conditions in a simpler grouped format.

Open Annex III All annexes
Total records
373
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4
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8

Records

373 total
Annex III 246

HYDROXYETHYL-3,4-METHYLENEDIOXYANILINE HCL

Hydroxyethyl-3,4-methylenedioxyaniline and its hydrochloride
CAS: 94158-14-2
EC: 303-085-5

Hair colourants can use severe allergic reactions Read and folow instructions

Product type
Annex III 247

HC BLUE NO 2

2,2'-[[4-[(2-Hydroxyethyl)amino]-3-nitrophenyl]imino]bisethanol (see note 17)
CAS: 33229-34-4
EC: 251-410-3

Can cause allergic reaction

Max concentration Product type
Annex III 248

3-NITRO-P-HYDROXYETHYLAMINOPHENOL

4-[(2-Hydroxyethyl)amino-3-nitrophenol
CAS: 65235-31-6
EC: 265-648-0

For (a) and (b): Hair colourants can use severe allergic reactions Read and follow intructions

Max concentration Product type
Annex III 249

4-NITROPHENYL AMINOETHYLUREA

1-(.beta.-Ureidoethyl)amino-4-nitrobenzene
CAS: 27080-42-8
EC: 410-700-1

For (a) and (b): Hair colourants can cause severe allergic reactions Read and follow instructions

Max concentration Product type
Annex III 25

ZINC PHENOLSULFONATE

Zinc 4-hydroxybenzene sulphonate
CAS: 127-82-2
EC: 204-867-8

Avoid contact with eyes

Max concentration Product type
Annex III 250

HC RED NO 10 + HC RED NO 11

1-amino-2-nitro-4-(2',3'-dihydroxypropyl)amino-5-chlorobenzene and 1,4-bis-(2',3'-dihydroxypropyl)amino-2-nitro-5-chlorobenzene and its salts
CAS: 95576-89-9 - 95576-92-4
EC: - -

Hair colourants can cause severe allergic reactions Read and folow instructions

Max concentration Product type
Annex III 250

HC Red No 10+ HC Red No 11

1-Amino-2-nitro-4-(2', 3'-dihydroxypropyl)amino-5-chloro-benzene + 1,4-bis-(2',3'-dihydroxypropyl)amino-2-nitro-5-chlorobenzene
CAS: 9556-89-9 - 95576-92-4

(a) After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 1,0% For (a) and (b): - Do not use with nitrosating agent…

Max concentration Product type
Annex III 251

2-CHLORO-6-ETHYLAMINO-4-NITROPHENOL

Phenol, 2-Chloro-6-(ethylamino)-4-nitro- and its salts
CAS: 131657-78-8
EC: 411-440-1

In combination with hydrogen peroxide the maximum use concentration upon application is 1.5% Not to be used after 31.12.2009

Max concentration Product type
Annex III 251

HC RED NO 7

2-(4-Amino-3-nitroanilino)ethanol
CAS: 24905-87-1
EC: 246-521-9

Hair colorants can cause severe allergic reactions

Max concentration Product type
Annex III 252

2-AMINO-6-CHLORO-4-NITROPHENOL

2-Amino-6-chloro-4-nitrophenol
CAS: 6358-09-4
EC: 228-762-1

(a) To be printed on the label: The mixing ratio. ‘ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type
Annex III 253

HC Yellow No. 4

2-[bis(2-Hydroxye­thyl)amino]-5-nitro­phenol
CAS: 59820-43-8
EC: 428-840-7

— Do not use with nitro­sating agents — Maximum nitrosamine content: 50 μg/kg — Keep in nitrite-free containers

Max concentration Product type
Annex III 253

HC Yellow No 4

2-[bis(2-Hydroxyethyl)amino]-5- nitrophenol
CAS: 59820-43-8
EC: 428-840-7

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 micrograme/Kg - Keep in nitrite-free containers

Max concentration Product type
Annex III 254

ACID RED 33

Disodium 5-amino-4-hydroxy-3-(phenylazo)naphathlene-2,7-disulphonate (see note 17); (CI 17200)
CAS: 3567-66-6
EC: 222-656-9

Hair dye substance in non-oxidative hair dye products

Max concentration Product type
Annex III 255

HC Yellow No 2

2-[(2-Nitrophenyl)amino] ethanol
CAS: 4926-55-0
EC: 225-555-8

To be printed on the label: Hair colorants can cause allergic reactions.

Max concentration Product type
Annex III 256

HC Orange No 1

4-[(2-Nitrophenyl)amino]phenol
CAS: 54381-08-7
EC: 259-132-4

Hair day substance in non-oxidative hair dye products

Max concentration Product type
Annex III 257

LAURETH-9

Laureth-9
CAS: 3055-99-0
EC: 221-284-4

(a) Leave-on products (b) Rinse-off products

Max concentration Product type
Annex III 258

HC Red No 1

2-Nitro-N1-phenyl-benzene-1,4- diamine
CAS: 2784-89-6
EC: 220-494-3

Hair colorants can cause severe allergic reactions.

Max concentration Product type
Annex III 259

HC Yellow No 9

1-Methoxy-3-(β-aminoethyl) amino-4-nitrobenzene, hydrochloride
CAS: 86419-69-4
EC: 415-480-1

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 microgram/Kg - Keep in nitrite-free containers

Max concentration Product type
Annex III 26

AMMONIUM MONOFLUOROPHOSPHATE

Ammonium monofluorophosphate
CAS: 20859-38-5 -- 66115-19-3
EC: - -- -

Contains ammonium monofluorophosphate. For any toothpaste with compounds containing fluorine in a concentration of 0,1 to 0,15 % calculated as F unless it is …

Max concentration Product type
Annex III 260

HC Yellow No 7

1-(4’-Aminophenylazo)-2-methyl- 4-(bis-2-hydroxyethyl) aminobenzene
CAS: 104226-21-3
EC: 146-420-6

Hair dye substance in oxidative hair dye products

Max concentration Product type
Annex III 261

HC Yellow No 13

N-(2-Hydroxyethyl)-2-nitro-4- trifluormethyl-aniline
CAS: 10442-83-8
EC: 443-760-2

To be printed on the label: Hair colorants can cause severe allergic reactions

Product type
Annex III 262

BASIC YELLOW 57

Benzenaminium, 3-[(4,5-dihydro- 3-methyl-5-oxo-1-phenyl-1H- pyrazol-4-yl)azo]-N,N,Ntrimethyl-, chloride
CAS: 68391-31-1
EC: 269-943-5

Hair dye substance in non-oxidative hair dye products

Max concentration Product type
Annex III 263

Disperse Black 9

Ethanol, 2,2′-[[4-[(4-aminophenyl) azo]phenyl]imino]bis-
CAS: 20721-50-0
EC: 243-98-5

Hair dye substance in non-oxidative hair dye products

Max concentration Product type
Annex III 264

HC Blue No 14

9,10-Anthracenedione, 1,4-bis [(2,3-dihydroxypropyl)amino]-
CAS: 99788-75-7
EC: 421-470-7

- Do not use with nitrosating agents - Maximum nitrosamine content: 50 microgram/Kg - Keep in nitrite-free containers

Max concentration Product type
Annex III 265

DISPERSE VIOLET 1

1,4-Diaminoanthraquinone
CAS: 128-95-0
EC: 204-922-6

Impurity of Disperse Red 15 in Disperse Violet 1 for hair dye formulations should be < 1 % (w/w)

Max concentration Product type
Annex III 266

HC RED No 3

Ethanol, 2-((4- amino-2-nitrophenyl)amino)-
CAS: 2871-01-4
EC: 220-701-7

For (a): To be printed on the label: The mixing ratio. For (a) and (b): “ Hair colorants can cause severe allergic reactions. Read and follow instructions. Thi…

Max concentration Product type
Annex III 267

BASIC RED 76

[7-Hydroxy-8-[(2- methoxyphenyl)azo]-2-naphthyl]trimethylammonium chloride
CAS: 68391-30-0
EC: 269-941-4

Hair dye substance non-oxidative hair dye products

Max concentration Product type
Annex III 269

2-Amino-5- Ethylphenol HCl

Phenol, 2-Amino- 5-Ethyl-, Hydrochloride

To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intended …

Product type
Annex III 269

BASIC RED 51

2-[[4-(Dimethylamino)phenyl]azo]-1,3- dimethyl-1H-imidazolium chloride
CAS: 77061-58-6
EC: 278-601-4

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 27

Sodium monofluorophosphate

CAS: 10163-15-2 -- 7631-97-2
EC: 233-433-0 -- 231-552-2

Contains sodium monofluorophosphate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is alre…

Max concentration Product type
Annex III 270

ACID RED 92

Fluorescein, 2',4',5',7'-tetrabromo-4,5,6,7- tetrachloro-, disodium salt (CI 45410)
CAS: 18472-87-2
EC: 242-355-6

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 272

P-AMINOPHENOL

4-Aminophenol
CAS: 123-30-8
EC: 204-616-2

(a) To be printed on the la­bel: The mixing ratio. “Hair colourants can cause severe allergic reac­tions. Read and follow instruc­tions.This product is not int…

Product type
Annex III 273

1-Hydroxyethyl-4,5- Diamino Pyrazole Sulfate

4,5-Diamino-1-(2- hydroxyethyl)-1H- pyrazole
CAS: 155601-30-2
EC: 429-300-3

To be printed on the label: The mixing ratio. Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intended fo…

Product type
Annex III 274

4-Formyl-1-Methylquinolinium-p-Toluenesulfonate

Quinolinium, 4- formyl-1-methyl-, salt with 4- methylbenzenesulfonic acid (1:1)
CAS: 223398-02-5
EC: 453-790-8

To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intended …

Product type
Annex III 275

Basic Yellow 87

Pyridinium, 1- methyl-4-[( methylphenylhydrazono)methyl]-, methyl sulfate
CAS: 68259-00-7
EC: 269-503-2

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 276

BASIC ORANGE 31

2-[(4-Aminophenyl)azo]-1,3- dimethyl-1H-imidazolium chloride
CAS: 97404-02-9
EC: 306-764-4

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 277

2,6-Diamino-3- ((Pyridine-3-yl)azo)Pyridine

2,6-Pyridinediamine, 3-(3- pyridinylazo)
CAS: 28365-08-4
EC: 421-430-9

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 278

BASIC VIOLET 2

4-((4-Amino-3- methylphenyl)(4- imino-3-methyl- 2,5-cyclohexadien-1- ylidene)methyl)-2- methylphenylamine monohydrochloride (CI 42520)
CAS: 3245-91-7
EC: 221-831-7

a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intend…

Max concentration Product type
Annex III 279

2,3-Diaminodihydropyrazolopyrazolone Dimethosulfonate

2,3-Diamino-6,7- dihydro-1H,5H- pyrazolo[1,2-a] Pyrazol-1-one dimethanesulfonate
CAS: 857035-95-1
EC: 469-500-8

To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not intended …

Product type
Annex III 28

Potassium monofluorophosphate

CAS: 14104-28-0
EC: 237-957-0

Contains potassium monofluorophosphate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is a…

Max concentration Product type
Annex III 280

Picramic Acid and Sodium Picramate

2-Amino-4,6-dinitrophenol and 2- amino-4,6-dinitrophenol, sodium salt
CAS: 96-91-3 / 831-52-7
EC: 202-544-6 / 212-603-8

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 281

2-Nitro-5-Glyceryl Methylaniline

1-Methylamino-2- nitro-5-(2,3-dihydroxy-propyloxy)- benzene
CAS: 80062-31-3
EC: 279-383-3

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 282

HC Blue 16

1-Propanaminium, 3-[[9,10-dihydro- 4-(methylamino)- 9,10-dioxo-1- anthracenyl] amino]-N,N- dimethyl-N- propyl-, bromide
CAS: 502453-61-4
EC: 481-170-7

— Do not use with nitrosating agents — Maximum nitrosamine content: 50 μg/kg — Keep in nitrite-free containers

Max concentration Product type
Annex III 283

5-Amino-6-Chloro-o- Cresol / 5-Amino-6-Chloro-o- Cresol HCl

3-amino-2-chlor- 6-methylphenol 3-amino-4-chloro- 6-methylphenol HCl
CAS: 84540-50-1 / 80419-48-3
EC: 283-144-9

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 284

2,2'-METHYLENEBIS 4-AMINOPHENOL HCL

Phenol, 2,2'- methylenebis[4- amino-], dihydrochloride
CAS: 27311-52-0 / 63969-46-0
EC: 440-850-3

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Max concentration Product type
Annex III 285

2,6-Diaminopyridine

Pyridine-2,6- diyldiamine
CAS: 141-86-6
EC: 205-507-2

(a) To be printed on the label: The mixing ratio. “ Hair colorants can cause severe allergic reactions. Read and follow instructions. This product is not inten…

Product type
Annex III 286

CETRIMONIUM CHLORIDE (1) / STRARTRIMONIUM CHLORIDE (1)

C16-alkyltrimethylammonium chloride C18-alkyltrimethyammonium chloride
CAS: 112-02-7
EC: 203-928-6

For purposes other than inhibiting the development of microorganisms in the product. The purpose has to be apparent from the presentation of the product.

Max concentration Product type
Annex III 287

BEHENTRIMONIUM CHLORIDE (1)

C22-alkyltrimethylammonium chloride
CAS: 17301-53-0
EC: 241-327-0

For purposes other than inhibiting the development of microorganisms in the product. The purpose has to be apparent from the presentation of the product.

Max concentration Product type

About this grouped view

This page groups together restricted cosmetic substances from Annex III, including records with warnings and conditions of use.

Use the detailed record pages to review restrictions, identifiers and related ingredient data.