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Annex III Entry 84 Allergen 17/10/2010

Linalool

1,6-Octadien-3-ol, 3,7-dimethyl-

Linalool is listed in Annex III and may only be used under the conditions shown in this record.

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Restricted substance— Annex III, EU Regulation 1223/2009
Entry: 84
Allergen
Declared fragrance allergen

This substance is on the EU list of fragrance allergens that must be named individually in the ingredient list, rather than being covered by the word "parfum", once it exceeds 0.001% in a leave-on product or 0.01% in a rinse-off product.

Declaration is a labelling duty under Article 19, not a restriction on use. See the allergen record

Chemical identity and properties

PubChem 2D chemical structure for CAS 78-70-6
CAS 78-70-6PubChem CID 6549

Linalool

Linalool is a monoterpenoid that is octa-1,6-diene substituted by methyl groups at positions 3 and 7 and a hydroxy group at position 3. It has been isolated from plants like Ocimum canum. It has a role as a volatile oil component, an antimicrobial agent, a fragrance and a plant metabolite. It is a monoterpenoid and a tertiary alcohol. — ChEBI

IUPAC name
3,7-dimethylocta-1,6-dien-3-ol
Molecular formula
C10H18O
Molecular weight
154.25 g/mol
Exact mass
154.135765193 Da
XLogP3
2.7
Topological polar surface area
20.2 Ų
Hydrogen-bond donors
1
Hydrogen-bond acceptors
1
Covalent units
1
Defined stereocentres
0

Also known as

LinalolLINALYL ALCOHOLbeta-Linalool3,7-Dimethyl-1,6-octadien-3-olallo-Ocimenol(+-)-Linalool1,6-Octadien-3-ol, 3,7-dimethyl-dl-Linalool
16 more reported names
2,6-Dimethylocta-2,7-dien-6-ol2,6-Dimethyl-2,7-octadien-6-olFEMA No. 2635(RS)-LinaloolDIABEXALLD81QY6I88ECHEBI:17580NSC-3789LicareolL 260-2muguolRefChem:41471LINALOOL, (A+-)-NDI 5957-methyl-3-methyleneocta-4,6-dien-2-ol201-134-4
Open full PubChem recordPubChem annotations3D structure image
External database identifiers

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Record details

Other restrictions

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds:
- 0.001% in leave-on products
- 0.01% in rinse-off products

INCI glossary name

Linalool

Chemical name

1,6-Octadien-3-ol, 3,7-dimethyl-

Chemical / IUPAC name

3,7-dimethyl-1,6-octadien-3-ol

Regulatory information

Regulation

(EC) 2009/1223

See every entry this act set

SCCS opinions

Identified ingredients

EU Fragrance Allergen

This substance is linked to an EU fragrance-allergen reference. Check the current Annex III entry for the declaration threshold and any additional conditions.

LINALOOL

Key data

CAS
78-70-6
EC
201-134-4
Annex
III
Entry number
84

Inventory links for Linalool

Inventory Restriction reference
Ref 41007

D-ALLO-OCIMENOL

CAS: 126-91-0
EC: 204-811-2
Inventory Restriction reference
Ref 41008

L-ALLO-OCIMENOL

CAS: 126-90-9
EC: 204-810-7
Inventory Restriction reference
Ref 35016

LINALOOL

CAS: 78-70-6
EC: 201-134-4

Direct matches are limited for this record, so nearby entries from Annex III are shown as well.

Annex III 82
Nearby record in the same annex

Farnesol

CAS: 4602-84-0
EC: 225-004-1
Annex III 85
Nearby record in the same annex

Benzyl benzoate

CAS: 120-51-4
EC: 204-402-9
Annex III 86
Nearby record in the same annex

Citronellol

CAS: 106-22-9/ 26489-01-0; 1117-61-9; 7540-51-4
EC: 203-375-0/ 247-737-6; 214-250-5; 231-415-7
Annex III 80
Nearby record in the same annex

ANISe ALCOHOL

CAS: 105-13-5
EC: 203-273-6
Annex III 87
Nearby record in the same annex

HEXYL CINNAMAL

CAS: 101-86-0
EC: 202-983-3
Annex III 78
Nearby record in the same annex

Geraniol

CAS: 106-24-1
EC: 203-377-1
Annex III 88
Nearby record in the same annex

Limonene

CAS: 138-86-3/ 7705-14-8; 5989-27-5; 5989-54-8
EC: 205-341-0/ 231-732-0; 227-813-5; 227-815-6
Annex III 77
Nearby record in the same annex

Coumarin

CAS: 91-64-5
EC: 202-086-7
Annex III 76
Nearby record in the same annex

Cinnamal

CAS: 104-55-2
EC: 203-213-9

What Annex III means for Linalool

Linalool is a restricted substance under Annex III of EU Cosmetics Regulation 1223/2009. Its use in cosmetics is only permitted under the specific conditions set out in the entry above, including applicable concentration limits, product type restrictions and required warning statements.

When including this substance in a formulation, all conditions — maximum concentration, product scope and warning labels — must be met simultaneously. Compliance with one condition does not override the others.

This record is linked to 5 CosIng inventory ingredients for name and identifier cross-reference. The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

  • Document conditions of use in the Product Information File (PIF).
  • This substance is a regulated fragrance allergen. Declare it on the label by INCI name above 0.001% in leave-on or 0.01% in rinse-off products.

Frequently asked questions

Linalool is listed in Annex III of EU Regulation 1223/2009 as a restricted substance. It may only be used under the conditions specified in the entry, including any maximum concentration, product type limitation and required warning statements shown above.

CAS 78-70-6 is the unique numerical identifier assigned to Linalool by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

Yes. Linalool is on the EU list of regulated fragrance allergens. It must be declared on the cosmetic product label by its INCI name when present above 0.001% in leave-on products or above 0.01% in rinse-off products, as required by EU Cosmetics Regulation 1223/2009.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.
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Source note for Annex III record Linalool

This page summarizes one Annex III record for Linalool from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex III conditions for Linalool, but confirm any final regulatory decision against the current official annex wording and source files.

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