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Restricted Cosmetic Substances — Annex III

Annex III of EU Cosmetics Regulation 1223/2009 lists substances that may only be used under specific conditions. This grouped page currently contains 375 records with restriction logic, concentration limits, warnings or product-type conditions to review.

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Annex III records

375 total

Annex III 377

Alpha-Arbutin

4-Hydroxyphenyl-alpha-D-glucopyranoside

CAS: 84380-01-8EC: 617-561-8

Hydroquinone levels shall remain as low as possible in formulations containing alpha-Arbutin and shall not be higher than the unavoidable trace level. From 1 …

Max concentration Product type

Annex III 378

Arbutin

4-Hydroxyphenyl-beta-D-glucopyranoside

CAS: 497-76-7EC: 207-850-3

Hydroquinone levels shall remain as low as possible in formulations containing alpha-Arbutin and shall not be higher than the unavoidable trace level. From 1 …

Max concentration Product type

Annex III 379

Silver

Silver (powder) [100 nm < particle diameter < 1 mm]

CAS: 7440-22-4EC: 231-131-3

(a) Toothpaste (b) Mouthwash

Max concentration Product type

Annex III 38

N,N',N'-Tris(polyoxyethylene)-N-hexadecylpropylenediamine dihydrofluoride

Contains N,N',N'-tris(polyoxyethylene)-N-hexadecylpropylenediamine dihydrofluoride For any toothpaste with compounds containing fluorine in a concentration of…

Max concentration Product type

Annex III 380

Hexyl Salicylate

Hexyl 2-hydroxybenzoate

CAS: 6259-76-3EC: 228-408-6

Not to be used in preparations for children under 3 years of age, with the exception of (d) “Toothpaste” and (f).

Max concentration Product type

Annex III 39

OCTADECENYLAMMONIUM FLUORIDE

Octadecenyl- Ammonium Fluoride

CAS: 36505-83-6

Contains octadecenyl-ammonium fluoride. For any toothpaste with compounds containing fluorine in a concentration of 0,1 to 0,15 % calculated as F unless it is …

Max concentration Product type

Annex III 4

AMMONIA

Ammonia

CAS: 7664-41-7 / 1336-21-6EC: 231-635-3 / 215-647-6

Above 2%: Contains ammonia

Max concentration

Annex III 40

SODIUM FLUOROSILICATE

Sodium Fluorosilicate

CAS: 16893-85-9EC: 240-934-8

Contains sodium fluorosilicate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is already l…

Max concentration Product type

Annex III 41

POTASSIUM FLUOROSILICATE

Potassium Fluorosilicate

CAS: 16871-90-2EC: 240-896-2

Contains potassium fluorosilicate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is alread…

Max concentration Product type

Annex III 42

Ammonium fluorosilicate

CAS: 16919-19-0EC: 240-968-3

Contains ammonium fluorosilicate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is already…

Max concentration Product type

Annex III 43

MAGNESIUM FLUOROSILICATE

Magnesium Fluorosilicate

CAS: 16949-65-8EC: 241-022-2

Contains magnesium fluorosilicate For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is alread…

Max concentration Product type

Annex III 44

DIMETHYLOL ETHYLENE THIOUREA

1,3-Bis(hydroxymethyl)imidazolidine-2-thione

CAS: 15534-95-9EC: 239-579-1

Contains Dimethylol ethylene thiourea

Max concentration Product type

Annex III 45

BENZYL ALCOHOL

Benzyl Alcohol

CAS: 100-51-6EC: 202-859-9

For purposes other than inhibiting the development of microorganisms in the product. This purpose has to be apparent from the presentation of the product. The …

Product type

Annex III 46

6-Methylcoumarin

CAS: 92-48-8EC: 202-158-8

The presence of the substance shall be indicated in the list of ingredients referred to in Article 19(1), point (g), when its concentration exceeds: — 0,001 % …

Max concentration Product type

Annex III 47

NICOMETHANOL HYDROFLUORIDE

Nicomethanol Hydrofluoride

CAS: 62756-44-9

Contains nicomethanol hydrofluoride For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is alre…

Max concentration Product type

Annex III 48

SILVER NITRATE

Silver nitrate

CAS: 7761-88-8EC: 231-853-9

Contains silver nitrate Rinse eyes immediately if product comes into contact with them

Max concentration Product type

Annex III 49

Selenium disulphide

Selenium sulfide

CAS: 7488-56-4EC: 231-303-8

Contains selenium disulphide Avoid contact with eyes or damaged skin

Max concentration Product type

Annex III 5

Chloramine-T

Tosylchloramide sodium (INN)

CAS: 127-65-1EC: 204-854-7

Max concentration

Annex III 50

Aluminium zirconium chloride hydroxide complexes AlxZr(OH)yClz and the aluminium zirconium chloride…

Do not apply to irritated or damaged skin

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Annex III 51

OXYQUINOLINE SULFATE

bis(8-hydroxyquinolinium) sulphate

CAS: 134-31-6EC: 205-137-1

(a) Stabilizer for hydrogen peroxide in rinse-off hair products (b) Stabilizer for hydrogen peroxide in leave-on hair products

Max concentration Product type

Annex III 52

METHYL ALCOHOL

Methanol

CAS: 67-56-1EC: 200-659-6

Denaturant for ethanol and isopropyl alcohol

Max concentration Product type

Annex III 53

Etidronic acid

(1-Hydroxyethylidene)diphosphonic acid and its salts

CAS: 2809-21-4EC: 220-552-8

(a) Hair product (b) Soap

Max concentration Product type

Annex III 54

1-Phenoxypropan-2-ol (8)

CAS: 770-35-4EC: 212-222-7

For purposes other than inhibiting the development of micro-organisms in the product. This purpose has to be apparent from the presentation of the product

Max concentration Product type

Annex III 56

MAGNESIUM FLUORIDE

Magnesium fluoride

CAS: 7783-40-6EC: 231-995-1

Contains magnesium fluoride For any toothpaste with compounds containing fluorine in a concentration of 0.1 to 0.15% calculated as F unless it is already labe…

Max concentration Product type

Annex III 57

STRONTIUM CHLORIDE

Strontium chloride hexahydrate

CAS: 10476-85-4EC: 233-971-6

Contains strontium chloride Frequent use by children is not advisable

Max concentration Product type

Annex III 58

STRONTIUM ACETATE

Strontium acetate hemihydrate

CAS: 543-94-2EC: 208-854-8

Contains strontium acetate Frequent use by children is not advisable

Max concentration Product type

Annex III 59

TALC

Talc: Hydrated magnesium silicate

CAS: 14807-96-6EC: 238-877-9

(a) Keep powder away from children's nose and mouth

Product type

Annex III 6

POTASSIUM CHLORATE / SODIUM CHLORATE

Chlorates of alkali metals

CAS: 3811-04-9 / 7775-09-9EC: 223-289-7 / 231-887-4

(a) Toothpaste (b) Other products

Max concentration Product type

Annex III 60

Fatty acid dialkylamides and dialkanolamides

- Do not use with nitrosating systems - Maximum secondary amine content: 5% (applies to raw materials) - Maximum nitrosamine content: 50 microgram/kg - Keep …

Max concentration

Annex III 61

Monoalkylamines, monoalkanolamines and their salts

- Do not use with nitrosating systems - Minimum purity: 99% - Maximum secondary amine content: 0.5% (applies to raw materials) - Maximum nitrosamine content:…

Max concentration

Annex III 62

Trialkylamines, trialkanolamines and their salts

(a) (b) - Do not use with nitrosating systems - Minimum purity: 99% - Maximum secondary amine content: 0.5% (applies to raw materials) - Maximum nitrosamine …

Max concentration Product type

Annex III 63

STRONTIUM HYDROXIDE

Strontium hydroxide

CAS: 18480-07-4EC: 242-367-1

Keep out of reach of children Avoid contact with the eyes

Max concentration Product type

Annex III 64

Strontium peroxide

CAS: 1314-18-7EC: 215-224-6

Avoid contact with eyes Rinse eyes immediately if product comes into contact with them For professional use only Wear suitable gloves

Max concentration Product type

Annex III 65

BENZALKONIUM CHLORIDE / BENZALKONIUM BROMIDE / BENZALKONIUM SACCHARINATE

Benzalkonium chloride, bromide and saccharinate (9)

CAS: 91080-29-4 / 63449-41-2 / 68391-01-5 / 68424-85-1 / 85409-22-9 / 68989-01-5EC: 293-522-5 / 264-151-6 / 269-919-4 / 270-325-2 / 287-089-1 / 273-545-7

Avoid contact with the eyes

Max concentration Product type

Annex III 66

Polyacrylamides

(a) Maximum residual acrylamide content 0.1mg/kg (b) Maximum residual acrylamide content 0.5mg/kg

Product type

Annex III 67

Amyl cinnamal

2-Benzylideneheptanal

CAS: 122-40-7EC: 204-541-5

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 69

Cinnamyl alcohol

CAS: 104-54-1EC: 203-212-3

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 70

Citral; Geranial; Neral

3,7-Dimethyl-2,6-octadienal; (E)-3,7-dimethylocta-2,6-dienal; (Z)-3,7-dimethylocta-2,6-dienal

CAS: 5392-40-5; 141-27-5; 106-26-3EC: 226-394-6; 205-476-5; 203-379-2

The presence of the substance or substances shall be indicated as ‘Citral’ in the list of ingredients referred to in Article 19(1), point (g), when the concent…

Annex III 71

Eugenol

Phenol, 2-methoxy-4-(2-propenyl)-

CAS: 97-53-0EC: 202-589-1

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on p…

Annex III 72

HYDROXYCITRONELLAL

Hydroxycitronellal

CAS: 107-75-5EC: 203-518-7

(a) (b) The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)(g) when its concentration exceeds: — 0,001 % in…

Max concentration Product type

Annex III 73

ISOEUGENOL

Phenol, 2-methoxy-4-(1-propenyl); (E)-2-methoxy-4-(prop-1-enyl)phenol;(trans-Isoeugenol); (Z)-2-methoxy-4-(prop-1-enyl)phenol;(cis-Isoeugenol)

CAS: 97-54-1; 5932-68-3; 5912-86-7EC: 202-590-7; 227-678-2; 227-633-7

(a) (b) The presence of the substance shall be indicated in the list of ingredients referred to in Article 19(1), point (g), when its concentration exceeds: — …

Max concentration Product type

Annex III 74

Amylcinnamyl alcohol

2-Pentyl-3-phenylprop-2-en-1-ol

CAS: 101-85-9EC: 202-982-8

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 75

Benzyl salicylate

CAS: 118-58-1EC: 204-262-9

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 76

Cinnamal

2-Propenal, 3-phenyl-

CAS: 104-55-2EC: 203-213-9

The presence of the substance must be indicated in the list of ingredients referred to in Article 6(1)g when its concentration exceeds: - 0.001% in leave-on p…

Annex III 77

Coumarin

2H-1-Benzopyran-2-one

CAS: 91-64-5EC: 202-086-7

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 78

Geraniol

2,6-Octadien-1-ol, 3,7-dimethyl-, (2E)-

CAS: 106-24-1EC: 203-377-1

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 8

N-substituted derivatives of p- Phenylenediamine and their salts; N- substituted derivatives of o-P…

(a) To be printed on the label: The mixing ratio. “ Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not inte…

Max concentration Product type

Annex III 80

ANISe ALCOHOL

4-Methoxybenzyl alcohol

CAS: 105-13-5EC: 203-273-6

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 81

Benzyl cinnamate

2-Propenoic acid, 3-phenyl-, phenylmethyl ester

CAS: 103-41-3EC: 203-109-3

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

Annex III 82

Farnesol

2,6,10-Dodecatrien-1-ol, 3,7,11-trimethyl-

CAS: 4602-84-0EC: 225-004-1

The presence of the substance must be indicated in the list of ingredients referred to in Article 19(1)g when its concentration exceeds: - 0.001% in leave-on …

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Annex III lists substances permitted only under defined conditions. This grouped view is built for quickly triaging 375 restricted-substance records before you open the full entry and check concentration limits, product scope and warnings.

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