CAS 1 record

CAS 12227-89-3

CAS 12227-89-3 matches 1 EU annex record across Annex II–VI of Regulation 1223/2009.

Chemical identity and properties

PubChem 2D chemical structure for CAS 12227-89-3
CAS 12227-89-3PubChem CID 16211978

Iron oxide (Fe3O4)

IUPAC name
oxoiron;oxo(oxoferriooxy)iron
Molecular formula
Fe3O4
Molecular weight
231.53 g/mol
Exact mass
231.784465 Da
Topological polar surface area
60.4 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
4
Covalent units
2
Defined stereocentres
0

Also known as

Ferriferrous OxideOxide, FerriferrousOxide, FerrosoferricRefChem:9235661317-61-9215-277-5Black Iron OxideC.I. 77499
16 more reported names
CHEBI:50821EPT 500ferric ferrous oxideFerrosoferric OxideIron (II, III) OxideIron ores, magnetiteiron(II) diiron(III) oxideMagnetic BlackXM0M87F357Iron Oxide BlackIron(II,III)oxideEINECS 235-442-5Iron Oxide Pigment BlackIron(II,III) oxide, CPIron Oxide BlackDISCONTINUEDoxo[(oxoferrio)oxy]iron; oxoiron

Evidence from additional scientific databases

NIH PubChem PUG-View
Exact identifier match16211978

Attributed physical-property, hazard, environmental and use annotations.

  • Physical Description: CBI; Other Solid Source: EPA Chemical Data Reporting (CDR)
  • Physical Description: CBI; Dry Powder; Wet Solid; Large Crystals; Wet Solid; Other Solid; Dry Powder; Dry Powder; Other Solid; Liquid; Other Solid; Dry Powder; Large Crystals; Liquid; Liquid; Dry Powder; Large Crystals Source: EPA Chemical Data Reporting (CDR)
  • Note: This chemical does not meet GHS hazard criteria for 47% (956 of 2034) of reports. Source: European Chemicals Agency (ECHA)
  • Signal: Warning Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: H252 (13%): Self-heating in large quantities; may catch fire [Warning Self-heating substances and mixtures]; H315 (32.3%): Causes skin irritation [Warning Skin corrosion/irritation]; H319 (32.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H335 (32.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] Source: European Chemicals Agency (ECHA)
  • Precautionary Statement Codes: P235, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement) Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 2034 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.; Reported as not meeting GHS hazard criteria per 956 of 2034 reports by companies.; There are 17 notifications provided by 1078 of 2034 reports by companies with hazard statement code(s).; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)
  • Note: This chemical does not meet GHS hazard criteria for 98.1% (355 of 362) of all reports. Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: Not Classified; Reported as not meeting GHS hazard criteria by 355 of 362 companies (only 1.9% companies provided GHS information). For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 362 reports by companies from 5 notifications to the ECHA C&L Inventory.; Reported as not meeting GHS hazard criteria per 355 of 362 reports by companies.; There are 4 notifications provided by 7 of 362 reports by companies with hazard statement code(s).; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)

Mapped by: Existing checksum-valid CAS to unique PubChem CID match. Retrieved: 2026-08-31. Open source record

Scientific classifications and hazard annotations provide context and do not replace the market-specific regulatory decision shown above.

Additional source coverage and match status
SourceResultChecked
NIH PubChem PUG-ViewExact match2026-08-31

A recorded no-match is useful evidence that the source was checked; it is not a claim that the substance does not exist elsewhere.

Retrieved from NIH PubChem on 2026-08-31 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Records for CAS 12227-89-3

1 total
No records found for this CAS number.

How CAS 12227-89-3 is used on this site

CAS 12227-89-3 is the Chemical Abstracts Service identifier used to pin this page to a specific substance. In the current dataset, 1 EU annex record shares this identifier, which helps you cross-check whether the same substance appears under one regulatory context or several.

Use this page when a supplier specification, SDS or raw-material dossier gives you CAS 12227-89-3 and you need to see every linked Annex II–VI record in one place. The entry cards above are the quickest route to concentration limits, warnings, annex placement and product-type conditions.