Skip to main content
Annex IV Entry 120 14/08/2020

Lazurite

CI 77007

Lazurite appears in Annex IV as a positive-list colorant entry for EU cosmetics.

Permitted colorant— Annex IV, EU Regulation 1223/2009
Entry: 120

Chemical identity and properties

PubChem 2D chemical structure for CAS 12769-96-9
CAS 12769-96-9PubChem CID 91667813

CI 77007

IUPAC name
hexaaluminum;hexasodium;bis(tetrathietane);hexasilicate
Molecular formula
Al6Na6O24S8Si6
Molecular weight
1108.9 g/mol
Exact mass
1107.343926 Da
Topological polar surface area
756.0 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
32
Covalent units
20
Defined stereocentres
0

Also known as

Ultramarine violetSodium aluminosilicate VioletUltramarine pinkUltramarine red1YZ11D167RCosmetic ultramarine blueEINECS 235-811-0EC 235-811-0
9 more reported names
CI 77013ALUMINUM SODIUM THIOSILICATE VIOLETRefChem:577089CI 77007 [INCI]235-811-0Ultramarineshexaaluminum;hexasodium;tetrathietane;hexasilicateUNII-1YZ11D167RHNMCSUXJLGGQFO-UHFFFAOYSA-N

Evidence from additional scientific databases

NIH PubChem PUG-View
Exact identifier match91667813

Attributed physical-property, hazard, environmental and use annotations.

  • Note: This chemical does not meet GHS hazard criteria for 100% (265 of 265) of all reports. Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: Not Classified; Reported as not meeting GHS hazard criteria by 265 of 265 companies. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 265 reports by companies from 1 notifications to the ECHA C&L Inventory.; Reported as not meeting GHS hazard criteria per 265 of 265 reports by companies.; There are 0 notifications provided by 0 of 265 reports by companies with hazard statement code(s).; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)

Mapped by: Existing checksum-valid CAS to unique PubChem CID match. Retrieved: 2026-08-31. Open source record

Scientific classifications and hazard annotations provide context and do not replace the market-specific regulatory decision shown above.

Additional source coverage and match status
SourceResultChecked
NIH PubChem PUG-ViewExact match2026-08-31

A recorded no-match is useful evidence that the source was checked; it is not a claim that the substance does not exist elsewhere.

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

PubChem 2D chemical structure for CAS 57455-37-5
CAS 57455-37-5PubChem CID 71587188

C.I. Pigment Blue 29

Lazurite is a mineral with formula of Na7Ca(Al6Si6O24)(S6+O4)(S3)1-·H2O or Na7Ca(Al6Si6O24)(SO4)(S3)1-·H2O. The corresponding IMA (International Mineralogical Association) number is IMA2020-H, IMA2021 s.p.. The IMA symbol is Lzr. RRUFF Project

Molecular formula
Al6Na8O24S3Si6
Molecular weight
994.5 g/mol
Exact mass
993.463108 Da
Topological polar surface area
581.0 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
27
Covalent units
21
Defined stereocentres
0

Also known as

Ultramarine BlueI39WR998BIC. I. 77007RefChem:917800611-533-9691-383-9Azure blueUNII-I39WR998BI
13 more reported names
LazuriteUltramarineLAZURITE [MI]ULTRAMARINE [MI]3516 ULTRA BLUE3522 ULTRA BLUEULTRAMARINE (MINERAL)IRERQBUNZFJFGC-UHFFFAOYSA-LULTRAMARINE BLUE (MINERAL)ULTRAMARINE BLUE CI 77007ALUMINUM SODIUM THIOSILICATE BLUELAZURITE (NA5(AL3(SIO4)3S))LAZURITE (CA2NA6(AL6(SIO4)6(SO4)S))

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Record details

Colour index or glossary

CI 77007

Chemical name

Lazurite

Chemical / IUPAC name

Lazurite

Color

Blue

Regulatory information

Regulation

(EC) 2009/1223

See every entry this act set

Identified ingredients

Key data

CAS
12769-96-9; 1317-97-1; 57455-37-5
EC
235-811-0; -; -;
Annex
Entry number
120

Inventory links for Lazurite

Inventory Restriction reference
Ref 32814

CI 77007

CAS: 12769-96-9 / 1302-83-6 / 57455-37-5
EC: 235-811-0 / 215-111-1 / -
Inventory Restriction reference
Ref 80486

ULTRAMARINES

CAS: 1302-83-6 / 1317-97-1 / 1345-00-2 / 11118-33-5 / 12703-66-1 / 12769-96-9 / 57455-37-5
EC: 215-111-1 / 215-711-3 / 235-811-0 / - / - / - / -

Direct matches are limited for this record, so nearby entries from Annex IV are shown as well.

Annex IV 119
Nearby record in the same annex

CI 77004

CAS: 1302-78-9
EC: 215-108-5
Annex IV 121
Nearby record in the same annex

CI 77015

CAS: 1309-37-1/1332-25-8
EC: - / 310-127-6
Annex IV 118
Nearby record in the same annex

CI 77002

CAS: 1332-73-6; 21645-51-2; 8011-94-7
EC: 215-573-4; 244-492-7; -
Annex IV 122
Nearby record in the same annex

CI 77120

CAS: 7727-43-7
EC: 231-784-4
Annex IV 117
Nearby record in the same annex

CI 77000

CAS: 7429-90-5
EC: 231-072-3
Annex IV 123
Nearby record in the same annex

CI 77163

CAS: 7787-59-9
EC: 232-122-7
Annex IV 116
Nearby record in the same annex

CI 75810

CAS: 11006-34-1; 8049-84-1
EC: 234-242-5; 232-471-5 ; 215-800-7 / 207-536-6 / 208-272-4 / 287-483-3 / 239-830-5 / 246-020-5
Annex IV 124
Nearby record in the same annex

CI 77220

CAS: 471-34-1
EC: 207-439-9 / 215-279-6
Annex IV 115
Nearby record in the same annex

CI 75470

CAS: 1260-17-9; 1343-78-8; -
EC: 215-724-4; 215-680-6; 215-023-3
Annex IV 125
Nearby record in the same annex

CI 77231

Annex IV 114
Nearby record in the same annex

CI 75300

CAS: 458-37-7; 94875-80-6
EC: 207-280-5; -
Annex IV 126a
Nearby record in the same annex

CI 77266

CAS: 1333-86-4
EC: 215-609-9

What Annex IV means for Lazurite

Lazurite is an approved colorant listed in Annex IV of EU Cosmetics Regulation 1223/2009. Only colorants on this positive list may be used to colour cosmetic products on the EU market.

Some colorants in Annex IV are restricted by product type — for example, prohibited from use around the eyes or in products applied to mucous membranes. Check the product type and conditions fields above before use.

This record is linked to 2 CosIng inventory ingredients for name and identifier cross-reference. The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

  • Confirm colorant is used only in permitted product types listed above.
  • Record the Colour Index number and CAS identifier in the ingredient declaration.

Frequently asked questions

Yes. Lazurite is included in Annex IV of EU Cosmetics Regulation 1223/2009 as a permitted colorant. Only colorants on this positive list may be used to colour cosmetic products in the EU. Check the product type conditions above for any use restrictions.

CAS 12769-96-9; 1317-97-1; 57455-37-5 is the unique numerical identifier assigned to Lazurite by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.

Source note for Annex IV record Lazurite

This page summarizes one Annex IV record for Lazurite from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex IV conditions for Lazurite, but confirm any final regulatory decision against the current official annex wording and source files.

Tools & next steps

Check your formula

Paste a full INCI list to detect Lazurite and other flagged EU annex records in one pass.

INCI Checker

Compare entries

Compare Lazurite side by side with another annex record to review differences in restrictions, concentrations and annex placement.

Compare

Browse the annex

See all records in Annex IV and compare regulatory conditions across substances in this annex.

Open Annex IV