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Annex II Entry 688 CMR15/10/2010

Binapacryl

Binapacryl is listed in Annex II as a prohibited substance for cosmetic products placed on the EU market.

Prohibited substance— Annex II, EU Regulation 1223/2009
Entry: 688
CMR

Chemical identity and properties

PubChem 2D chemical structure for CAS 485-31-4
CAS 485-31-4PubChem CID 10234

Binapacryl

2-sec-butyl-4,6-dinitrophenyl 3-methylbut-2-enoate is an enoate ester obtained by formal condensation of the carboxy group of 3,3-dimethylacrylic acid with the phenolic hydroxy group of dinoseb. It is a C-nitro compound and an enoate ester. It is functionally related to a dinoseb. ChEBI

IUPAC name
(2-butan-2-yl-4,6-dinitrophenyl) 3-methylbut-2-enoate
Molecular formula
C15H18N2O6
Molecular weight
322.31 g/mol
Exact mass
322.11648630 Da
XLogP3
4.6
Topological polar surface area
118.0 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
6
Covalent units
1
Defined stereocentres
0

Also known as

MorocideAcricidAmboxDapacrylDinapacrylMorrocidDinoseb methacrylateNiagara 9044
16 more reported names
HOE 2784 OADinoseb, 3,3-dimethylacryl esterFMC 9044HOE 2784NIA 90442-(1-Methylpropyl)-4,6-dinitrophenyl 3-methyl-2-butenoateENT 25,7932-sec-Butyl-4,6-dinitrophenyl senecioate3-Methylcrotonic acid 2-sec-butyl-4,6-dinitrophenyl ester2,4-Dinitro-6-sec-butylphenyl 2-methylcrotonate2-sec-Butyl-4,6-dinitrophenyl 3-methylcrotonate3,3-Dimethylacrylic acid 2-sec-butyl-4,6-dinitrophenyl ester3-Methyl-2-butenoic acid 2-sec-butyl-4,6-dinitrophenyl ester2-sec-Butyl-4,6-dinitrophenyl-3,3-dimethylacrylate2-sec-Butyl-4,6-dinitrophenyl 3-methyl-2-butenoate4,6-Dinitrophenyl-2-sec-butyl-3-methyl-2-butenonate
External database identifiers

Retrieved from NIH PubChem on 2026-08-31 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Record details

Chemical name

Binapacryl

Chemical / IUPAC name

2-sec-butyl-4,6-dinitrophenyl-3-methylcrotonate

Regulatory information

Key data

Annex
Entry number
688

Direct matches are limited for this record, so nearby entries from Annex II are shown as well.

Annex II 686
Nearby record in the same annex

4-Nitrobiphenyl

CAS: 92-93-3
EC: 202-204-7
Annex II 685
Nearby record in the same annex

2-Nitroanisole

CAS: 91-23-6
EC: 202-052-1
Annex II 683
Nearby record in the same annex

2-Nitropropane

CAS: 79-46-9
EC: 201-209-1
Annex II 682
Nearby record in the same annex

Acrylonitrile

CAS: 107-13-1
EC: 203-466-5

What Annex II means for Binapacryl

Binapacryl is listed as a prohibited substance under Annex II of EU Cosmetics Regulation 1223/2009 and must not be intentionally added. Article 17 separately addresses unintended small quantities that are technically unavoidable under good manufacturing practice and compatible with the Article 3 safety requirement.

Formulators must screen their ingredients and raw materials to ensure none contain this substance. Suppliers should provide documentation confirming absence when requested.

The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

  • Verify this substance is absent from all raw materials and finished formulations.
  • Request absence confirmation or CoA from raw material suppliers.
  • Document the screening result in the Product Information File (PIF).
  • This substance has CMR classification. Review the CMR table above and verify current Annex II/III status before use.

Frequently asked questions

Yes. Binapacryl is listed in Annex II of EU Cosmetics Regulation 1223/2009 and is prohibited as an intentionally added cosmetic ingredient. Article 17 provides a narrow exception for unintended small quantities that are technically unavoidable under good manufacturing practice, provided the product remains safe under Article 3.

CAS 485-31-4 is the unique numerical identifier assigned to Binapacryl by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

Binapacryl has a CMR (carcinogenic, mutagenic or reprotoxic) classification under EU CLP Regulation. Under Article 15 of EU Cosmetics Regulation 1223/2009, CMR substances of category 1A or 1B are prohibited in cosmetics unless specifically permitted. Category 2 CMR substances may be used only if assessed safe by the SCCS. Always verify current annex status and any applicable derogations before use.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.

Source note for Annex II record Binapacryl

This page summarizes one Annex II record for Binapacryl from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex II conditions for Binapacryl, but confirm any final regulatory decision against the current official annex wording and source files.

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