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InventoryRef 3286115/10/2010

CITRONELLOL

3,7-Dimethyl-6-octen-1-ol

CITRONELLOL is linked to 1 EU annex record on this page. Inventory note: III/86.

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Regulatory evidence by market

This matrix separates verified ingredient rules from sources that are mapped but not yet imported. No imported rule does not mean the ingredient is permitted.

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MarketEvidence statusRecordsSource language
European UnionEvidence linked
Restricted entry found
Open this evidence		1English and EU languages
Great BritainEvidence linked
Restricted
Open this evidence		1English
CanadaSource mapped
Official source mapped; ingredient rule not imported
0English and French
New ZealandEvidence linked
Restricted
Open this evidence		2English
ASEANSource mapped
Official source mapped; ingredient rule not imported
0English and national languages
ChinaSource mapped
Official source mapped; ingredient rule not imported
0Chinese with selected English material
JapanSource mapped
Official source mapped; ingredient rule not imported
0Japanese; official English translation available
South KoreaSource mapped
Official source mapped; ingredient rule not imported
0Korean with some English names
United StatesSource mapped
Official source mapped; ingredient rule not imported
0English
AustraliaSource mapped
Official source mapped; ingredient rule not imported
0English
BrazilSource mapped
Official source mapped; ingredient rule not imported
0Portuguese with INCI crosswalks
IndiaEvidence linked
Restricted
Open this evidence		1English and Hindi
Saudi ArabiaSource mapped
Official source mapped; ingredient rule not imported
0Arabic and English

Chemical identity and properties

PubChem 2D chemical structure for CAS 106-22-9
CAS 106-22-9CAS 26489-01-0PubChem CID 8842

Citronellol

(±)-β-citronellol has been reported in Ambrosiozyma monospora, Artemisia princeps, and other organisms with data available. — LOTUS - the natural products occurrence database

IUPAC name
3,7-dimethyloct-6-en-1-ol
Molecular formula
C10H20O
Molecular weight
156.26 g/mol
Exact mass
156.151415257 Da
XLogP3
3.2
Topological polar surface area
20.2 Ų
Hydrogen-bond donors
1
Hydrogen-bond acceptors
1
Covalent units
1
Defined stereocentres
0

Also known as

Cephrol3,7-DIMETHYL-6-OCTEN-1-OL6-Octen-1-ol, 3,7-dimethyl-ElenolRodinol2,3-Dihydrogeraniol2,6-Dimethyl-2-octen-8-olCitronellol, dl-
16 more reported names
Dihydrogeraniol565OK72VNFCHEBI:50462RefChem:29968Citronellol (ex. Java citronella oil)203-375-0247-737-6beta-CitronellolDL-Citronellol(+/-)-beta-Citronellol.beta.-CitronellolC10H20OCitronellol (Standard)beta-Citronellol, 95%NSC 8779NSC-8779
Open full PubChem recordPubChem annotations3D structure image
External database identifiers

Evidence from additional scientific databases

EMBL-EBI ChEBI
Exact identifier matchCHEBI:50462

citronellol

A monoterpenoid that is oct-6-ene substituted by a hydroxy group at position 1 and methyl groups at positions 3 and 7.

Formula
C10H20O
Average mass
156.269 g/mol
Monoisotopic mass
156.15142 Da
Formal charge
0
  • monoterpenoid — is a (CHEBI:25409)
  • plant metabolite — has role (CHEBI:76924)
  • plant metabolite — has role (CHEBI:76924)
  • monoterpenoid — is a (CHEBI:25409)
Additional curated names
3,7-dimethyloct-6-en-1-ol2,3-Dihydrogeraniol2,6-Dimethyl-2-octen-8-ol3,7-Dimethyl-6-octen-1-olCephrolElenolbeta-Citronellol
Cross-references from this source
  • CAS: 106-22-9 — ChemIDplus
  • CAS: 106-22-9 — NIST Chemistry WebBook
  • REGISTRY_NUMBER: 1362474 — Reaxys
  • MANUAL_X_REF: Citronellol — Wikipedia

Mapped by: Exact CAS cross-reference in the ChEBI compound record. Source updated: 2015-08-17. Retrieved: 2026-08-31. Open source record

NIH PubChem PUG-View
Exact identifier match8842

Attributed physical-property, hazard, environmental and use annotations.

  • Signal: Warning Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: H315 (95.7%): Causes skin irritation [Warning Skin corrosion/irritation]; H317 (99.6%): May cause an allergic skin reaction [Warning Sensitization, Skin]; H319 (65.1%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H411 (15.8%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard] Source: European Chemicals Agency (ECHA)
  • Precautionary Statement Codes: P261, P264, P264+P265, P272, P273, P280, P302+P352, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement) Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 1657 reports by companies from 29 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]; H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]; H319 (17.5%): Causes serious eye irritation [Warning Serious eye damage/eye irritation] Source: European Chemicals Agency (ECHA)
  • Precautionary Statement Codes: P261, P264, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement) Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 103 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)
  • Signal: Warning Source: Hazardous Substances Data Bank (HSDB)
  • GHS Hazard Statements: H315: Causes skin irritation [Warning Skin corrosion/irritation]; H317: May cause an allergic skin reaction [Warning Sensitization, Skin]; H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H401: Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard] Source: Hazardous Substances Data Bank (HSDB)
  • Precautionary Statement Codes: P261, P264, P264+P265, P272, P273, P280, P302+P352, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement) Source: Hazardous Substances Data Bank (HSDB)
  • Toxicity Summary: IDENTIFICATION AND USE: Citronellol has been found in nature, and it has been reported in about 70 essential oils. It is registered for pesticide use in the USA but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses. It is also used in perfumery. HUMAN EXPOSURE AND TOXICITY: Adult male volunteers with no known allergic reactions were patch-tested on their back for 48 hr with 32% citronellol. After 48 hr, patches were removed and the skin was cleaned of any residual test material. Moderate irritation was observed. A patch test using a 1% concentration of citronellol in acetone gave a positive reaction in subjects allergic to citronella oil. ANIMAL STUDIES: Citronellol applied full strength to intact or abraded rabbit skin for 24 hr under occlusion was moderately irritating. Severe irritation was observed in rabbits and guinea pigs exposed to 100% compound (unoccluded) for 24, 48 or 72 hr. Citronellol was not mutagenic when tested in Salmonella typhimurium strains TA98 and TA100 in the presence and absence of metabolic activation. ECOTOXICITY STUDIES: Golden Orfe (Leuciscus idus) were exposed to th Source: Hazardous Substances Data Bank (HSDB)
  • Environmental Bioconcentration: An estimated BCF of 177 was calculated in fish for citronellol(SRC), using a log Kow of 3.91(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC), provided the compound is not metabolized by the organism(SRC). Source: Hazardous Substances Data Bank (HSDB)
  • Environmental Fate: TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 94(SRC), determined from a structure estimation method(2), indicates that citronellol is expected to have high mobility in soil(SRC). Volatilization of citronellol from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 2.1X10-5 atm-cu m/mole(SRC), derived from its vapor pressure, 0.02 mm Hg(3), and water solubility, 200 mg/L(4). Even though the vapor pressure is low environmentally at standard temperature and pressure, there is a detectable odor; therefore, citronellol may volatilize from dry soil(SRC). An 80-90% of Theoretical BOD using activated sludge in the OECD 301F test(5) suggests that biodegradation is an important environmental fate process in soil(SRC). Citronellol was also classified as readily biodegradable by the results of the OECD 301C test (modified MITI) with 65% degradation in 4 weeks(6) and by a DOC Method F test (100% biodegradation in 15 days)(6). Citronellol absorbs at wavelengths >290 nm(7) and, therefore, may be susceptible to direct photolysis on soil surfaces exposed to sunlight(SRC). Source: Hazardous Substances Data Bank (HSDB)
  • Environmental Fate: AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 94(SRC), determined from a structure estimation method(2), indicates that citronellol is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(3) based upon an estimated Henry's Law constant of 2.1X10-5 atm-cu m/mole(SRC), derived from its vapor pressure, 0.02 mm Hg(4), and water solubility, 200 mg/L(5). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 2.4 and 21 days, respectively(SRC). According to a classification scheme(6), an estimated BCF of 177(SRC), from its log Kow of 3.91(7) and a regression-derived equation(2), suggests the potential for bioconcentration in aquatic organisms is high(SRC). An 80-90% of Theoretical BOD using activated sludge in the OECD 301F test(8) suggests that biodegradation is an important environmental fate process in water(SRC). Citronellol was also classified as readily biodegradable by the results of the OECD 301C test (modified MITI) with 65% degradation in 4 weeks(9) and by a DOC Method F test (100% biodegradation in 15 days)(9). Citronellol i Source: Hazardous Substances Data Bank (HSDB)
  • Environmental Fate: ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), citronellol, which has a vapor pressure of 0.02 mm Hg at 25 °C(2), is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase citronellol is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 2.3 hours(SRC), calculated from its rate constant of 1.70X10-10 cu cm/molecule-sec at 24 deg(3). Citronellol is also degraded in the atmosphere by reaction with ozone and nitrate radicals. The half-life for the reaction with ozone is estimated to be 1.1 hours(SRC), calculated from its rate constant of 2.4X10-16 cu cm/molecule-sec at 24 °C(3). The half-life for the reaction with nitrate radicals is estimated to be 4 minutes(SRC), calculated from its rate constant of 1.21X10-11 cu cm/molecule-sec at 24 °C(4). The nitrate radical (NO3) is the dominant atmospheric oxidant during the night-time in most atmospheric environments(5), therefore, night-time degradation appears to be a major fate process for citronellol(SRC). Citronellol absorbs at wavelengths >290 Source: Hazardous Substances Data Bank (HSDB)
  • Sources/Uses: l-Form: in rose and geranium oils; d-Form: in Ceylon and Java citronella oils; Used in perfumery; [Merck Index] Permitted for use as an inert ingredient in non-food pesticide products; [EPA] Present in over 30 essential oils, fruits, edible plants, wine, beer, and black tea; Active ingredient in pesticide used to control mites on agricultural crops, ornamentals, and landscapes; Also extensively used as fragrance (detergents, soaps, lotions, perfumes, etc.), as a flavoring agent, and component of citronella oil (used in candles, sprays, oils, and insect repellents); [EPA BRADs] Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
  • Industrial Processes with risk of exposure: Farming (Pesticides) [Category: Industry] Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
  • Uses: For citronellol (USEPA/OPP Pesticide Code: 167004) ACTIVE products with label matches. /SRP: Registered for use in the USA but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./ Source: Hazardous Substances Data Bank (HSDB)
  • Uses: Reported uses (ppm):; Table: Reported uses (ppm): (Flavor and Extract Manufacturers' Association, 1994) [Table#6302] Source: Hazardous Substances Data Bank (HSDB)
  • Uses: In perfumery Source: Hazardous Substances Data Bank (HSDB)
  • Uses: Citronellol is one of the components responsible for the insect repellent properties of citronella oil ... Citronellol finds extensive use in floral fragrances and in flavors for citrus and other fruit notes. Its stability makes it particularly useful in fragrances for soaps, detergents, and other household products. Citronellol is also important as an intermediate in the synthesis of a number of other aroma chemicals ... Citronellol is the key feedstock for the synthesis of rose oxide. Source: Hazardous Substances Data Bank (HSDB)
  • Uses: Citronellol is one of the most widely used fragrance materials, particularly for rose notes and for floral compositions in general. As flavor material, citronellol is added for bouquetting purposes to citrus compositions. It is the starting material for numerous citronellyl esters and for hydroxydihydrocitronellol, an intermediate in the production of hydroxydihydrocitronellal. Source: Hazardous Substances Data Bank (HSDB)

Mapped by: Existing checksum-valid CAS to unique PubChem CID match. Retrieved: 2026-08-31. Open source record

Scientific classifications and hazard annotations provide context and do not replace the market-specific regulatory decision shown above.

Additional source coverage and match status
SourceResultChecked
EMBL-EBI ChEBIExact match2026-08-31
NIH PubChem PUG-ViewExact match2026-08-31

A recorded no-match is useful evidence that the source was checked; it is not a claim that the substance does not exist elsewhere.

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

PubChem 2D chemical structure for CAS 1117-61-9
CAS 1117-61-9PubChem CID 101977

beta-CITRONELLOL, (R)-

(R)-(+)-citronellol is a citronellol that is oct-6-ene substituted by a hydroxy group at position 1 and methyl groups at positions 3 and 7 (the 3R-enantiomer). It is an enantiomer of a (S)-(-)-citronellol. — ChEBI

IUPAC name
(3R)-3,7-dimethyloct-6-en-1-ol
Molecular formula
C10H20O
Molecular weight
156.26 g/mol
Exact mass
156.151415257 Da
XLogP3
3.2
Topological polar surface area
20.2 Ų
Hydrogen-bond donors
1
Hydrogen-bond acceptors
1
Covalent units
1
Defined stereocentres
1

Also known as

D-Citronellol(R)-3,7-Dimethyl-6-octen-1-ol(R)-beta-Citronellol6-Octen-1-ol, 3,7-dimethyl-, (R)-UNII-P01OUT964KP01OUT964KCITRONELLOL, D-EINECS 214-250-5
16 more reported names
AI3-00204Purifying relief soothing gel essence6-Octen-1-ol, 3,7-dimethyl-, (theta)-RefChem:54520Hydrating Treatment TonerHydrating extra concentrate serum214-250-5(R)-Citronellol(R)-3,7-Dimethyloct-6-en-1-ol(R)-(+)-beta-Citronellol(+)-citronellol6-Octen-1-ol, 3,7-dimethyl-, (3R)-(R)-(+)-Citronellol(+)-beta-Citronellol(R)-(+)-ss-Citronellol(R)-(+)-beta -Citronellol
Open full PubChem recordPubChem annotations3D structure image
External database identifiers

Evidence from additional scientific databases

NIH PubChem PUG-View
Exact identifier match101977

Attributed physical-property, hazard, environmental and use annotations.

  • Signal: Warning Source: European Chemicals Agency (ECHA)
  • GHS Hazard Statements: H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]; H317 (86%): May cause an allergic skin reaction [Warning Sensitization, Skin]; H319 (36.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]; H335 (14%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] Source: European Chemicals Agency (ECHA)
  • Precautionary Statement Codes: P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement) Source: European Chemicals Agency (ECHA)
  • ECHA C&L Notifications Summary: Aggregated GHS information provided per 279 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.; Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. Source: European Chemicals Agency (ECHA)

Mapped by: Existing checksum-valid CAS to unique PubChem CID match. Retrieved: 2026-08-31. Open source record

Scientific classifications and hazard annotations provide context and do not replace the market-specific regulatory decision shown above.

Additional source coverage and match status
SourceResultChecked
NIH PubChem PUG-ViewExact match2026-08-31

A recorded no-match is useful evidence that the source was checked; it is not a claim that the substance does not exist elsewhere.

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

PubChem 2D chemical structure for CAS 7540-51-4
CAS 7540-51-4PubChem CID 7793

Beta-citronellol, (S)-

(S)-(-)-citronellol is a citronellol that is oct-6-ene substituted by a hydroxy group at position 1 and methyl groups at positions 3 and 7 (the 3S-enantiomer). It is an enantiomer of a (R)-(+)-citronellol. — ChEBI

IUPAC name
(3S)-3,7-dimethyloct-6-en-1-ol
Molecular formula
C10H20O
Molecular weight
156.26 g/mol
Exact mass
156.151415257 Da
XLogP3
3.2
Topological polar surface area
20.2 Ų
Hydrogen-bond donors
1
Hydrogen-bond acceptors
1
Covalent units
1
Defined stereocentres
1

Also known as

l-Citronellol(S)-3,7-dimethyloct-6-en-1-ol(-)-Citronellol(S)-citronellol(S)-(-)-beta-Citronellol(-)-3,7-Dimethyloct-6-en-1-ol6-Octen-1-ol, 3,7-dimethyl-, (3S)-CITRONELLOL, L-
16 more reported names
6-Octen-1-ol, 3,7-dimethyl-, (S)-3S,7-dimethyloct-6-en-1-ol8RSY5Y5658(-)-(s)-citronellolEINECS 231-415-7(S)-(-)-.BETA.-CITRONELLOL6-Octen-1-ol, 3,7-dimethyl-, (-)-AI3-09552.BETA.-CITRONELLOL, (S)-RefChem:567275(S)-(-)-citronellol(-)-beta-Citronellolbeta-Rhodinol(3S)-citronellol(S)-(-)-3,7-Dimethyl-6-octen-1-ol(-)-fA-Citronellol
Open full PubChem recordPubChem annotations3D structure image
External database identifiers

Retrieved from NIH PubChem on 2026-09-02 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Inventory details for CITRONELLOL

INCI name

CITRONELLOL

Description

3,7-Dimethyl-6-octen-1-ol

Record provenance

Inventory reference
32861
Imported identity
CITRONELLOL
Source update
15/10/2010
European Commission CosIng source notes
Annex III Restriction reference
Entry 86

Citronellol

CAS: 106-22-9/ 26489-01-0; 1117-61-9; 7540-51-4
EC: 203-375-0/ 247-737-6; 214-250-5; 231-415-7

Key data

CAS
106-22-9 / 26489-01-0 / 7540-51-4 / 1117-61-9
EC
203-375-0 / 247-737-6 / 231-415-7 / 214-250-5
Restriction
III/86
Function
PERFUMING
Used for perfume and aromatic raw materials.

Official EU ingredient-name evidence

The ingredient name exactly matches the official 2025 EU glossary of common ingredient names.

#6621 · CITRONELLOL
Declared fragrance allergen

This substance is on the EU list of fragrance allergens that must be named individually in the ingredient list, rather than being covered by the word "parfum", once it exceeds 0.001% in a leave-on product or 0.01% in a rinse-off product.

Declaration is a labelling duty under Article 19, not a restriction on use. See the allergen record

Ingredients with overlapping formulation functions

CITRAL ETHYLENEGLYCOL CYCLIC ACETALPERFUMING
CITRAL-ACID ISOMERIZEDPERFUMING
CITROLPERFUMING
CITRONELLAL DIMETHYL ACETALPERFUMING
CITRONELLYL BENZOATEPERFUMING
CITRONELLYL BUTYRATEPERFUMING
CITRONELLYL CROTONATEPERFUMING
CITRONELLYL ETHYL ETHERPERFUMING

Additional official and scientific sources

11 external databases to check this identity in

Each link searches that source for this identity. What each source is, and its legal weight

ECHA CHEM / Information on chemicalsPubChem PUG RESTEU Safety Gate cosmetic product alertsECHA CHEMUS EPA CompToxCosmetic Ingredient Review safety assessmentsFDA Global Substance Registration SystemILO/WHO International Chemical Safety CardsJapan NITE-CHRIPNIOSH Pocket Guide to Chemical HazardsOECD eChemPortal

How CITRONELLOL appears in the CosIng inventory

The CosIng inventory lists CITRONELLOL as a cosmetic ingredient and this page links it to 1 annex record. The inventory entry captures names and identifiers, while the annex record shows where the substance is prohibited, restricted or positively listed in EU cosmetics law.

CITRONELLOL is also tagged with 1 cosmetic function in the official data. Function labels describe intended use, but they do not replace regulatory review of linked annex records before formulation or labelling work.

Frequently asked questions

CITRONELLOL appears in the EU CosIng inventory and has linked annex records. Check the annex records above for applicable restrictions, concentration limits and conditions of use. Annex II listing means prohibited; Annex III means restricted; Annexes IV, V and VI mean permitted under specified conditions.

The restriction field for CITRONELLOL reads: "III/86". This is the restriction note recorded in the CosIng inventory for this ingredient. For authoritative conditions and limits, always refer to the linked annex entries above.

According to the EU CosIng inventory, CITRONELLOL carries the following function designation(s):

CAS 106-22-9 / 26489-01-0 / 7540-51-4 / 1117-61-9 may appear across multiple EU annex records. Viewing the CAS lookup page shows all Annex II–VI entries sharing this identifier, which is useful for identifying cross-annex regulatory status of the same chemical substance.

Use the INCI Checker to screen a full ingredient list across selected markets, or compare this substance across all supported market datasets.
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Source note for CITRONELLOL

This page combines the CosIng inventory entry for CITRONELLOL with 1 linked Annex II–VI record from the local dataset built from public European Commission cosmetic ingredient materials.

Use this inventory page to research CITRONELLOL and compare linked records, but verify restrictions and legal status against the current official source text and law before making regulatory decisions.

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