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About this allergen

Limonene is declared far more often than it is added. It is a major constituent of citrus oils, and its Annex III entry carries something the others do not — a peroxide limit on the raw material.

  • Annex III entry 88: declaration above 0.001% leave-on and 0.01% rinse-off.
  • The peroxide value of the substance must be under 20 mmoles/L.
  • That limit applies to the substance as supplied, not to the finished product.
  • It occurs naturally in citrus and many other essential oils, so it is often declared without having been added as such.

Limonene is not usually an ingredient someone chose. It is a major component of orange, lemon and bergamot oils, and of a great many other botanicals, so a formula containing a citrus oil contains limonene whether or not anyone intended it. That is why it appears on so many ingredient lists, and why a reader can encounter it in a product that describes itself as naturally fragranced.

The entry adds a condition that no other allergen in the set carries: the peroxide value of the substance must be less than 20 mmoles/L. Limonene oxidises on contact with air, and it is the oxidation products — hydroperoxides formed over time — that sensitise, more than limonene itself. The regulation therefore constrains the material's state rather than its quantity.

The entry is explicit that this limit applies to the substance and not to the finished cosmetic product, which makes it a raw-material specification question. It is answered by the supplier's certificate of analysis and by how the material is stored and handled, not by anything measurable in the tube at the end.

Checked against

EU AllergenCAS 5989-27-5

LIMONENE — EU Regulated Fragrance Allergen

d-Limonene, Dipentene

LIMONENE is included in this site's EU fragrance-allergen reference set. The general declaration threshold is above 0.001% in leave-on products or above 0.01% in rinse-off products, but any linked Annex II or III conditions also apply.

This page links LIMONENE to 1 annex record in the EU cosmetics dataset. Declared on the label when present above 0.001% in leave-on products or 0.01% in rinse-off products under EU Cosmetics Regulation 1223/2009 Annex III.

Leave-on products
> 0.001%
Label declaration required
Rinse-off products
> 0.01%
Label declaration required

Regulatory status

INCI name

LIMONENE

CAS number

5989-27-5

Synonyms

d-Limonene, Dipentene

Declaration requirement

Must be declared on the cosmetic product label when present above 0.001% in leave-on products or above 0.01% in rinse-off products.

Legal basis

EU Cosmetics Regulation 1223/2009, Annex III

Additional chemical sources

Search the same identity in independent official chemistry and hazard databases. These sources provide context and do not replace the EU labelling rule above.

ECHA CHEM

EU substance information and CLP classification where available.

Search this identity

US EPA CompTox

EPA chemistry, exposure and toxicity data search.

Search this identity

Annex records for LIMONENE

Why LIMONENE matters for EU labelling

LIMONENE has a dedicated fragrance-labelling reference page and currently links to 1 annex record. Regulation (EU) 2023/1545 also added 56 allergens and updated existing entries, so current Annex III evidence remains authoritative.

Declared on the label when present above 0.001% in leave-on products or 0.01% in rinse-off products under EU Cosmetics Regulation 1223/2009 Annex III.

Allergen declaration is a labelling obligation, not an automatic ban. If additional Annex II or Annex III conditions apply through the linked records above, those conditions must be checked separately from the label declaration thresholds.

Frequently asked questions

LIMONENE is included in the fragrance-allergen labelling reference. A labelling rule does not by itself establish that an ingredient is permitted: an Annex II prohibition or additional Annex III restriction may also apply. Check every linked current annex record above.

Declaration of LIMONENE is mandatory when the concentration exceeds 0.001% (10 ppm) in leave-on cosmetic products or 0.01% (100 ppm) in rinse-off products. Below these thresholds, label declaration is not required but may be made voluntarily.

The concentration threshold applies to the allergen in the finished product. When the allergen is contributed by a fragrance blend, the allergen content of the blend (provided by the fragrance supplier) must be multiplied by the percentage of blend used in the formula. If the calculated total allergen concentration exceeds the threshold, it must be declared on the label.

Use the INCI Checker to paste your ingredient list. It checks dedicated allergen references including LIMONENE and scans all Annex II–VI entries, including the expanded Annex III records introduced or updated under Regulation (EU) 2023/1545.

CAS 5989-27-5 identifies LIMONENE in the EU regulatory databases. The annex records linked above show all Annex II–VI entries that share this CAS number, including any additional restriction or prohibition conditions beyond the allergen labelling requirement.

Source note for LIMONENE

This page combines the EU allergen-labelling rule for LIMONENE with 1 linked Annex II–VI record drawn from the current local dataset.

Use this page to review labelling logic for LIMONENE, but verify any final compliance decision against the current official allergen rules, annex text and source files.

Tools & next steps

Check your formula

Scan a full INCI list for LIMONENE, the other EU allergens and any linked annex restrictions.

INCI Checker

Allergen references

Browse the site's dedicated allergen references and continue to the complete current Annex III records from LIMONENE.

View all allergens

Calculate the threshold

Calculate the finished-product level of LIMONENE contributed by a fragrance or raw-material blend.

Allergen calculator

Annex entries by CAS

View all EU annex records sharing CAS 5989-27-5.

View CAS records