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Annex VI Entry 27a 28/07/2020

TITANIUM DIOXIDE (NANO)

Titanium dioxide (nano)

Key data

Source and verification note

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Record details

INCI glossary name

TITANIUM DIOXIDE (NANO)

Chemical name

Titanium dioxide (nano)

Chemical / IUPAC name

Titanium dioxide [1];Anatase (TiO2) [2];Rutile (TiO2) [3]

Maximum concentration

25% - In case of combined use of Titanium Dioxide and Titanium Dioxide (nano), the sum shall not exceed the limit of 25%.

Warnings

Not to be used in applications that may lead to exposure of the end-user's lungs by inhalation
Only nanomaterials having the following characteristics are allowed:
— purity ≥ 99 %,
— rutile form, or rutile with up to 5 % anatase, with crystalline structure and physical appearance as clusters of spherical, needle, or lanceolate shapes,
— median particle size based on number size distribution ≥ 30 nm,
— aspect ratio from 1 to 4,5, and volume specific surface area ≤ 460 m2/cm3,

— coated with Silica, Hydrated Silica, Alumina, Aluminium Hydroxide, Aluminium Stearate, Stearic Acid, Trimethoxycaprylylsilane, Glycerin, Dimethicone, Hydrogen Dimethicone, Simethicone;

or coated with one of the follow­ing combinations:
—Silica at a maximum concen­tration of 16 % and Cetyl Phosphate at a maximum concentration of 6 %,
—Alumina at a maximum con­centration of 7 % and Manga­nese Dioxide at a maximum concentration of 0,7 % (not to be used in lip products), —Alumina at a maximum con­centration of 3 % and Triethoxycaprylylsilane at a maximum concentration of 9 %,

— photocatalytic activity ≤ 10 % compared to corresponding non-coated or non-doped re­ference,
— nanoparticles are photostable in the final formulation.

Wording of conditions of use and warnings:
For face products containing Tita­nium Dioxide (nano) coated with the combination Alumina and Manganese Dioxide: Not to be used on the lips.

Regulatory information

Regulation

(EU) 2019/1857

SCCS opinions

Opinion on Titanium Dioxide,Opinion for clarification of the meaning of the term "sprayable
applications/products" for the nano forms of Carbon Black CI 77266, Titanium Oxide and Zinc Oxide,OPINION ON Titanium Dioxide (nano form) as UV-Filter in sprays,OPINION ON Titanium Dioxide (nano form) coated with Cetyl Phosphate, Manganese Dioxide or Triethoxycaprylylsilane as UV-filter in dermally applied cosmetic

Direct matches are limited for this record, so nearby entries from Annex VI are shown as well.

Annex III 321
Shared CAS number

TITANIUM DIOXIDE

CAS: 13463-67-7/ 1317-70-0/ 1317-80-2
EC: 236-675-5/ 215-280-1/ 215-282-2
Annex VI 27
Shared CAS number

TITANIUM DIOXIDE

CAS: 13463-67-7[1]/ 1317-70-0[2]/ 1317-80-2[3]
EC: 236-675-5[1] /215-280-1[2]/215-282-2 [ 3]
Annex VI 26
Nearby record in the same annex

Polysilicone-15

CAS: 207574-74-1
EC: 426-000-4

About this record

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