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Annex III Entry 136 17/05/2013

Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate

Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate is listed in Annex III and may only be used under the conditions shown in this record.

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Restricted substance— Annex III, EU Regulation 1223/2009
Entry: 136

Chemical identity and properties

PubChem 2D chemical structure for CAS 1866-31-5
CAS 1866-31-5PubChem CID 641423

Allyl Cinnamate

Allyl cinnamate is a cinnamate ester. — ChEBI

IUPAC name
prop-2-enyl (E)-3-phenylprop-2-enoate
Molecular formula
C12H12O2
Molecular weight
188.22 g/mol
Exact mass
188.083729621 Da
XLogP3
3.0
Topological polar surface area
26.3 Ų
Hydrogen-bond donors
0
Hydrogen-bond acceptors
2
Covalent units
1
Defined stereocentres
0

Also known as

Propenyl cinnamateVinyl carbinyl cinnamateCINNAMIC ACID, ALLYL ESTER2-Propenoic acid, 3-phenyl-, 2-propenyl esterAllyl beta-phenylacrylateFEMA No. 20222-Propen-1-yl 3-phenyl-2-propenoateN8149Z51V9
16 more reported names
2-Propenoic acid, 3-phenyl-, 2-propen-1-yl esterNSC-20972prop-2-en-1-yl (2Z)-3-phenylprop-2-enoateRefChem:554853217-477-8Allyl 3-phenylacrylateAllyl 3-phenyl-2-propenoateCinnamic Acid Allyl EsterAllylester kyseliny skoricoveNSC 20972CHEBI:191535Allyl (E)-3-phenylprop-2-enoatetrans-Allyl cinnamate2-Propenyl 3-phenyl-2-propenoateEINECS 217-477-8Allylester kyseliny skoricove [Czech]
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External database identifiers

Retrieved from NIH PubChem on 2026-08-31 by checksum-valid CAS matching. Chemical properties do not replace the regulatory decision on this page.

Record details

Other restrictions

Level of free allyl alcohol in the ester should be less than 0.1%

Chemical name

Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate

Regulatory information

Regulation

(EC) 2013/344

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SCCS opinions

Identified ingredients

Key data

CAS
1866-31-5
EC
217-477-8
Annex
III
Entry number
136

Inventory links for Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate

Inventory Restriction reference
Ref 41335

ALLYL CINNAMATE

CAS: 1866-31-5
EC: 217-477-8

Direct matches are limited for this record, so nearby entries from Annex III are shown as well.

Annex III 133
Nearby record in the same annex

Terpinolene

CAS: 586-62-9
EC: 209-578-0
Annex III 140
Nearby record in the same annex

Allyl caproate

CAS: 123-68-2
EC: 204-642-4
Annex III 131
Nearby record in the same annex

Alpha-Terpinene

CAS: 99-86-5
EC: 202-795-1
Annex III 142
Nearby record in the same annex

Allyl octanoate

CAS: 4230-97-1
EC: 224-184-9

What Annex III means for Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate

Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate is a restricted substance under Annex III of EU Cosmetics Regulation 1223/2009. Its use in cosmetics is only permitted under the specific conditions set out in the entry above, including applicable concentration limits, product type restrictions and required warning statements.

When including this substance in a formulation, all conditions — maximum concentration, product scope and warning labels — must be met simultaneously. Compliance with one condition does not override the others.

This record is linked to 1 CosIng inventory ingredient for name and identifier cross-reference. The page also surfaces 12 related annex records with overlapping identifiers, annex logic or naming patterns.

Compliance checklist

  • Document conditions of use in the Product Information File (PIF).

Frequently asked questions

Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate is listed in Annex III of EU Regulation 1223/2009 as a restricted substance. It may only be used under the conditions specified in the entry, including any maximum concentration, product type limitation and required warning statements shown above.

CAS 1866-31-5 is the unique numerical identifier assigned to Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate by the Chemical Abstracts Service. In cosmetic compliance work, the CAS number is used to cross-reference the substance across regulatory databases, raw material specifications and safety assessment reports. Multiple EU annex entries may share the same CAS number if the same substance appears under different conditions or in different annexes.

Use the INCI Checker tool on this site to paste your full ingredient list (INCI) and scan it against all Annex II–VI entries. The tool highlights any ingredients that match restricted, prohibited or allergen-flagged records. This is useful for rapid compliance screening of finished product formulas or raw material declarations.
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Source note for Annex III record Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate

This page summarizes one Annex III record for Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate from public European Commission cosmetic materials and adds linked inventory or identifier matches when available.

Use this record page to review Annex III conditions for Allyl cinnamate; 2-Propenyl 3-Phenyl-2-propenoate, but confirm any final regulatory decision against the current official annex wording and source files.

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